硝酸铈(Ⅳ)铵

• 产品号: A12882
• CAS号: 16774-21-3
• 分子式: CeH8N8O18
• 分子量: 548.22232
• 纯 度: 98+%

产品别名

• 标题: Cerium(IV) ammonium nitrate
• IUPAC标准名: λ^4-cerium(4+) ion diammonium hexanitrate
• IUPAC传统名: λ^4-cerium(4+) ion diammonium hexanitrate
• 别名: Ammonium cerium(IV) nitrate; CAN

产品登记号

• MDL号: MFCD00151121
• CAS号: 16774-21-3
• 默克索引号: 141992
• EC号: 240-827-6

产品性质

• 纯度: 98+%
• GHS危险声明: H272-H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 欧盟危险性物质标志: 氧化性(Oxidising) (O)
• GHS警示性声明: P221-P210-P305+P351+P338-P302+P352-P405-P501A
• 危险公开号: 8-36/37/38
• 安全公开号: 17-26-37-60
• TSCA收录: 是
• 联合国危险货物等级: 5.1
• 联合国危险货物编号: UN1477
• 联合国危险货物包装类别(PG): II

参考文献

• Catalyst for mild, selective opening of epoxides: Tetrahedron, 47, 9861 (1991).
• The direct conversion of aldehydes to nitriles in aqueous NH₃, under extremely mild conditions, is mediated by CAN: Synlett, 262 (2003).
• Versatile oxidizing agent. For reviews, see: Chem. Rev., 92, 29 (1992); J. Prakt. Chem./ Chem. Ztg., 336, 470 (1994); Synlett, 834 (1999); 3014 (2005); Acc. Chem. Res., 37, 21 (2004). Examples of oxidations with CAN:
• For formation of dithioacetals, see 1,2-Ethanedithiol, L12865. For cleavage of dithioacetals, see 1,3-Dithiane, A10505.
• Selective conversion of alcohols to aldehydes: J. Chem. Soc., 5777 (1965); J. Org. Chem., 32, 2349, 3865 (1967). Oxidation of benzylic methyl groups to aldehydes or acetates: J. Org. Chem., 31, 2033 (1966); 45, 3906 (1980). For selective oxidation of 2-methylpyrroles to the aldehydes, see: Tetrahedron Lett., 36, 4345 (1995). Phenols to quinones: Synthesis, 347 (1973); Liebigs Ann. Chem., 1655, 1669 (1986). Cleavage of vic-diols to ketones and ɑ-hydroxy ketones to acids: J. Org. Chem., 34, 869 (1969); Synthesis, 560 (1972). Conversion of ɑ-diketones and a-keto esters to carboxylic acids: J. Org. Chem., 71, 4516 (2006). Oxidative bisdecarboxylation of malonic acid derivatives: Tetrahedron Lett., 29, 769 (1988). Regeneration of carbonyl compounds from oximes or semicarbazones: Can. J. Chem., 47, 145 (1969); Synthesis, 347 (1973). Catalytic deprotection of Boc protected alcohols, amines and thiols: Tetrahedron Lett., 37, 2035 (1996). Debenzylation of N-benzyl tertiary amines: J. Chem. Soc., Perkin 1, 3765 (2000). Decomplexation of transition metal π-complexes: Org. Synth. Coll., 8, 460 (1993). Oxidative addition of olefins to the ɑ-position of ketones: Tetrahedron Lett., 28, 5357 (1987); Synth. Commun., 18, 1841 (1988).