1-硝基丙烷

• 产品号: A11975
• CAS号: 108-03-2
• 分子式: C3H7NO2
• 分子量: 89.09318
• 纯 度: 98%

产品别名

• 标题: 1-Nitropropane
• IUPAC标准名: 1-nitropropane
• IUPAC传统名: 1-nitropropane

产品登记号

• EC号: 203-544-9
• MDL号: MFCD00007407
• CAS号: 108-03-2
• 默克索引号: 146627
• Beilstein号: 506236

产品性质

• 纯度: 98%
• 沸点: 131-132°C
• 密度: 0.998
• 闪点: 34°C(93°F)
• 熔点: -108°C
• 折射率: 1.4020
• GHS危险声明: H226-H302-H312-H332
• 欧盟危险性物质标志: X
• GHS警示性声明: P210-P241-P303+P361+P353-P302+P352-P403+P235-P501A
• 危险公开号: 10-20/21/22
• RTECS编号: TZ5075000
• 安全公开号: 2-9
• TSCA收录: 是
• 联合国危险货物等级: 3
• 联合国危险货物编号: UN2608
• 联合国危险货物包装类别(PG): III

参考文献

• For an example of condensation with an aldehyde (Henry reaction), promoted by KF in IPA, see: Org. Synth. Coll., 9, 242 (1998). Other conditions recommended for the Henry reaction include the use of the basic ion-exchange resin Amberlyst? A-21, A17956: Liebigs Ann. Chem., 1994, 1235; J. Org. Chem., 59, 5466 (1994); Tetrahedron, 52, 1677 (1996), and aqueous NaOH in the presence of a surfactant-type catalyst (hexadecyltrimethylammmonium chloride): J. Org. Chem., 62, 425 (1997). Improved yields in condensations with cycloalkanones were obtained by the use of high pressure: Angew. Chem. Int. Ed., 23, 617 (1984).
• Primary nitro-compounds are converted to nitrile oxides by reaction with POCl₃ in pyridine: J. Org. Chem., 42, 3956 (1977). For example of 1,3-dipolar addition reaction of the nitrile oxide to give an isoxazole, see Ethyl (E)-3-(1-pyrrolidinyl)crotonate, L00461.
• For discussion of conditions for formation and chemistry of the ɑɑ- and ɑ?- dilithio derivatives, see: Encyclopedia of Reagents for Organic Synthesis, L. A. Paquette, Ed., Wiley, Chichester (1995), vol. 3, p. 1946.