N-甲基甲酰苯胺

• 产品号: A11829
• CAS号: 93-61-8
• 分子式: C8H9NO
• 分子量: 135.16316
• 纯 度: 99%

产品别名

• 标题: N-Methylformanilide
• IUPAC标准名: N-methyl-N-phenylformamide
• IUPAC传统名: N-methylformanilide

产品登记号

• CAS号: 93-61-8
• MDL号: MFCD00003283
• EC号: 202-262-3
• Beilstein号: 636496

产品性质

• 纯度: 99%
• 沸点: 242-244°C
• 密度: 1.095
• 闪点: 126°C(258°F)
• 熔点: 9-13°C
• 折射率: 1.5610
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• GHS警示性声明: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• 危险公开号: 36/37/38
• 安全公开号: 26-37
• TSCA收录: 是

参考文献

• Has also been used for the conversion of aryllithiums to aldehydes: J. Chem. Soc. (C), 1700 (1969).
• Component of Vilsmeier's original reagent for the formylation of reactive aromatics via the iminium salts: Ber., 60, 119 (1927); much used in earlier work, where N,N-Dimethylformamide, A13547, is often now preferred due to lower cost, greater thermal stability of the iminium salt and easier separation of the by-products (water-soluble in the case of DMF). The N-methylformanilide reagent is still occasionally preferred because of its higher electrophilic potential, although this may be partially offset by its greater steric demand. For examples of its use, see: Org. Synth. Coll., 3, 96 (1955); 4, 915 (1963). Review: Adv. Org. Chem., 9, 225 (1976). Monograph: Synthesis Using Vilsmeier Reagents, C. M. Marson, P. R. Giles, CRC Press, Boca Raton, FL (1994).