五水合硝酸铋(III)

• 产品号: A11748
• CAS号: 10035-06-0
• 分子式: BiH10N3O14
• 分子量: 485.0715
• 纯 度: 98%

产品别名

• 标题: Bismuth(III) nitrate pentahydrate
• IUPAC标准名: bismuth(3+) ion pentahydrate trinitrate
• IUPAC传统名: bismuth(3+) ion pentahydrate trinitrate

产品登记号

• MDL号: MFCD00149157
• 默克索引号: 141271
• CAS号: 10035-06-0
• EC号: 233-791-8

产品性质

• 纯度: 98%
• 密度: 2.83
• 熔点: 30°C dec.
• GHS危险声明: H272-H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 欧盟危险性物质标志: 氧化性(Oxidising) (O)
• GHS警示性声明: P221-P210-P305+P351+P338-P302+P352-P405-P501A
• 危险公开号: 8-36/37/38
• 安全公开号: 17-26-37-60
• TSCA收录: 是
• 联合国危险货物等级: 5.1
• 联合国危险货物编号: UN1477
• 联合国危险货物包装类别(PG): II

参考文献

• Useful, easily handled oxidizing and nitrating agent in organic synthesis. Montmorillonite KSF acidic clay impregnated with bismuth nitrate was found to be an excellent reagent for high-yield aromatic nitration: Tetrahedron Lett., 41, 8017 (2000). Phenols can be nitrated with the salt itself in acetone, or without solvent: J. Org. Chem., 70, 9071 (2005). In the presence of montmorillonite, alcohols can be oxidized to carbonyl compounds: Synth. Commun., 31, 2691 (2001). Reagent for deprotection of oximes: Synthesis, 1010 (2001), and hydrazones: Synth. Commun., 32, 1917 (2001). Thioamides and thioureas are readily converted to their oxo-analogs: Tetrahedron Lett., 44, 591 (2003).
• Catalyst for a convenient, high-yield Michael addition of various substrates, including amines, imidazoles and indoles, to enones: J. Org. Chem., 68, 2109 (2003). Efficient catayst for tetrahydropyranylation and depyranylation of alcohols: Eur. J. Org. Chem., 4891 (2005).
• For a brief feature on uses of the reagent in organic synthesis, see: Synlett, 2699 (2005).