1,4,8,11-四氮环十四烷

• 产品号: A11516
• CAS号: 295-37-4
• 分子式: C10H24N4
• 分子量: 200.32436
• 纯 度: 98+%

产品别名

• 标题: 1,4,8,11-Tetraazacyclotetradecane
• IUPAC标准名: 1,4,8,11-tetraazacyclotetradecane
• IUPAC传统名: cyclam
• 别名: Cyclam

产品登记号

• MDL号: MFCD00005105
• CAS号: 295-37-4
• EC号: 206-039-1
• Beilstein号: 111811

产品性质

• 纯度: 98+%
• 熔点: 184-188°C
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• GHS警示性声明: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• 危险公开号: 36/37/38
• RTECS编号: XA5254800
• 安全公开号: 26-37
• 保存注意事项: Air Sensitive
• TSCA收录: 否

参考文献

• Nitrogen analogue of the crown ethers (see Appendix 2), forming stable complexes with metal ions: Inorg. Chem., 4,1102, 1109 (1965); Can. J. Chem., 48, 1481 (1970). For examples of use as a versatile ligand in coordination chemistry, see: Acc. Chem. Res., 11, 392 (1978); J. Chem. Soc., Chem. Commun., 1322 (1986); 1075 (1987); 156 (1988); Inorg. Chem., 26, 908 (1987); J. Am. Chem. Soc., 110, 3679 (1988).
• Complex with iron(II) triflate is an effective epoxidation catalyst: J. Am. Chem. Soc., 113, 7052 (1991).
• The Ni(II) complex catalyzes the novel electrochemical reaction of epoxides with carbon dioxide to give good yields of cyclic carbonates: J. Chem. Soc., Chem. Commun., 43 (1995). A similar system catalyzes the electrochemical intramolecular reductive cyclization of a series of o-halogenated aryl alkenes: Tetrahedron Lett., 36, 4429 (1995):
  
• For use in synthesis of molecules with electroactive cavities, see (Ferrocenylmethyl)trimethylammonium iodide, 39399.