环己烯

• 产品号: A11359
• CAS号: 110-83-8
• 分子式: C6H10
• 分子量: 82.1436
• 纯 度: 99%

产品别名

• 标题: Cyclohexene
• IUPAC标准名: cyclohexene
• IUPAC传统名: cyclohexene

产品登记号

• 默克索引号: 142727
• EC号: 203-807-8
• MDL号: MFCD00001539
• CAS号: 110-83-8
• Beilstein号: 906737

产品性质

• 纯度: 99%
• 沸点: 83-85°C
• 密度: 0.811
• 闪点: -20°C(-4°F)
• 熔点: -104°C
• 折射率: 1.4460
• GHS危险声明: H225-H301-H304
• 欧盟危险性物质标志: X
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• GHS警示性声明: P210-P241-P301+P310-P303+P361+P353-P405-P501A
• 危险公开号: 11-22-65
• RTECS编号: GW2500000
• 安全公开号: 9-16-23-33-36-60-62
• TSCA收录: 是
• 联合国危险货物等级: 3
• 联合国危险货物编号: UN2256
• 联合国危险货物包装类别(PG): II

参考文献

• Protection of the phenolic OH of tyrosine as the cyclohexyl ether has been effected with BF₃ etherate. The group can be cleaved with HF or HBr/AcOH: J. Am. Chem. Soc., 100, 3559 (1978).
• Hydrogen donor in catalytic hydrogen-transfer reactions, usually with palladium. For reviews, see: Chem. Rev., 74, 567 (1974); 85, 129 (1985). Examples:
• Hydrogenolysis of benzyloxycarbonyl groups: Synthesis, 685 (1976). Simultaneous cleavage of benzyl and benzyloxycarbonyl groups: J. Chem. Soc., Perkin 1, 490 (1977). Cleavage of benzyl ethers: Synthesis, 396 (1981). With FeCl₃, reduction of aryl carbonyl groups to methylene: J. Chem. Soc., Chem. Commun., 757 (1976).
• Conditions have been described for work-up of the ozonide to give the monoacetal of the dialdehyde, the aldehydo-ester, or the dimethyl acetal of the methyl ester: Org. Synth. Coll., 7, 168 (1990).
• Undergoes allylic acetoxylation, catalyzed by Palladium(II) acetate, 10516, in the presence of MnO₂ and 1,4-benzoquinone: Org. Synth. Coll., 8, 137 (1993).