丙酮肟

• 产品号: A10802
• CAS号: 127-06-0
• 分子式: C3H7NO
• 分子量: 73.09378
• 纯 度: 98%

产品别名

• 标题: Acetone oxime
• IUPAC标准名: N-(propan-2-ylidene)hydroxylamine
• IUPAC传统名: acetone oxime
• 别名: 2-Propanone oxime; Acetoxime

产品登记号

• Beilstein号: 1560146
• EC号: 204-820-1
• CAS号: 127-06-0
• 默克索引号: 1475
• MDL号: MFCD00002118

产品性质

• 纯度: 98%
• 沸点: 133-135°C
• 密度: 0.901
• 闪点: 60°C(140°F)
• 熔点: 60-63°C
• GHS危险声明: H228
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• GHS警示性声明: P210-P241-P280-P240-P370+P378A
• 危险公开号: 11
• RTECS编号: AL6825000
• TSCA收录: 是
• 联合国危险货物等级: 4.1
• 联合国危险货物编号: UN1325
• 联合国危险货物包装类别(PG): III

参考文献

• Aldehydes and ketones can be converted to their oximes in high yield by an exchange process involving heating with acetone oxime in acetic acid at 110^o: J. Prakt. Chem., 331, 870 (1989).
• N-Protected form of hydroxylamine. For O-alkylation with sodium bromoacetate, and acid hydrolysis to O-carboxymethylhydroxylamine hydrochloride, see: Org. Synth. Coll., 3, 172 (1955).
• For use of this and other simple oximes in the formation, by DCC-coupling, of active esters of N-protected oligopeptides, which react with C-protected amino acids to give peptides in high yield, see: Chem. Pharm. Bull., 17, 2937 (1969). See Appendix 6.