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• 产品号: A10355
• CAS号: 110-91-8
• 分子式: C4H9NO
• 分子量: 87.12036
• 纯 度: 99%

产品别名

• 标题: Morpholine
• IUPAC标准名: morpholine
• IUPAC传统名: morpholine

产品登记号

• EC号: 203-815-1
• 默克索引号: 146277
• CAS号: 110-91-8
• Beilstein号: 102549
• MDL号: MFCD00005972

产品性质

• 纯度: 99%
• 沸点: 129°C
• 密度: 1.007
• 闪点: 35°C(95°F)
• 熔点: -5°C
• 折射率: 1.4540
• GHS危险声明: H314-H226-H302-H312-H332
• 欧盟危险性物质标志: X
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• GHS警示性声明: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
• 危险公开号: 10-20/21/22-34
• RTECS编号: QD6475000
• 安全公开号: 23-36-45
• 保存注意事项: Hygroscopic
• TSCA收录: 是
• 联合国危险货物等级: 8
• 联合国危险货物编号: UN2054
• 联合国危险货物包装类别(PG): I

参考文献

• Reagent for the cleavage of Fmoc protecting groups in peptide synthesis (see 9-Fluorenylmethyl chloroformate, A11683): J. Am. Chem. Soc., 92, 5748 (1970); J. Org. Chem., 37, 3404 (1972). See Appendix 6 for peptide reagents.
• In the Kindler modification of the Willgerodt reaction, aryl ketones are converted to ω-arylalkanoic acids by reaction with sulfur and an amine, usually morpholine: Org. Synth. Coll., 9, 99 (1998); reviews: Org. React., 3, 83 (1946); Synthesis, 358 (1975).
• Lithium morpholide adds to aromatic aldehydes at low temperature, a useful means for the protection of the aldehyde group in lithiations: Tetrahedron Lett., 25, 4213 (1981); J. Org. Chem., 48, 2356 (1983).
• Chlorination with hypochlorite gives N-chloromorpholine, a useful reagent in strongly acid media for the selective chlorination of activated aromatics: Org. Synth. Coll., 8, 167 (1993), and references therein.