过硼酸钠四水合物

• 产品号: A10189
• CAS号: 10486-00-7
• 分子式: B2H16Na2O14
• 分子量: 307.72018
• 纯 度: 97%

产品别名

• 标题: Sodium perborate tetrahydrate
• IUPAC标准名: disodium tetrahydroxy-1,2,4,5,3,6-tetraoxadiborinane-3,6-diuide hexahydrate
• IUPAC传统名: disodium hexahydrate perborate

产品登记号

• CAS号: 10486-00-7
• MDL号: MFCD00149231
• 默克索引号: 148652
• EC号: 239-172-9

产品性质

• 纯度: 97%
• 密度: 1.73
• 熔点: 60°C dec.
• GHS危险声明: H360-H318-H302-H335
• 欧盟危险性物质标志: 有毒(Toxic) (T)
• GHS警示性声明: P261-P280-P281-P305+P351+P338-P405-P501A
• 危险公开号: 61-62-37-41
• RTECS编号: SC7350000
• 安全公开号: 53-45-47
• 保存注意事项: Hygroscopic
• TSCA收录: 是

参考文献

• In combination with triflic acid for hydroxylation of aromatics: Synlett, 39 (1991).
• In combination with acetic anhydride, cyclic acetals are cleaved to their respective esters: Synlett., 329 (1995).
• For phase-transfer oxidation of alcohols to ketones, catalyzed by Chromium(VI) oxide, 12522, see: Synth. Commun., 21, 575 (1991).
• For a brief feature on uses in synthesis, see: Synlett, 2513 (2006).
• Useful, inexpensive oxidant. Reviews: Chemtech, 566 (1991); Tetrahedron, 51, 6145 (1995); Synthesis, 1325 (1995); J. Chem. Soc., Perkin 1, 471 (2000). Examples: Oxidation of secondary alcohols to ketones, and ɑ-hydroxy acids to keto acids: Synthesis, 765 (1989). Mild epoxidation of ɑ?-unsaturated ketones: Synth. Commun., 19, 3579 (1989); Tetrahedron Lett., 36, 663 (1995). Partial hydrolysis of nitriles to amides: Tetrahedron, 45, 3299 (1989); Synth. Commun., 20, 563 (1990). Oxidation (in AcOH) of sulfides to sulfoxides or sulfones, arylamines to nitro compounds, and Baeyer-Villiger oxidation of ketones to esters: Tetrahedron, 43, 1753 (1987). Oxidation (in AcOH) of aromatic aldehydes to acids: Tetrahedron, 45, 3299 (1989); or oximes to nitro compounds: Synlett, 337 (1992). Oxidative conversion of organoboranes to alcohols: Org. Synth. Coll., 9, 522 (1998).