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丙酮

产品号 L10407 公司名称 Alfa Aesar
CAS号 67-64-1 公司网站 http://www.alfa.com
分子式 C3H6O 电 话
分子量 58.07914 传 真
纯 度 99+% 电子邮件
保 存 Chembase数据库ID: 105716

产品价格信息

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产品别名

标题
Acetone
IUPAC标准名
propan-2-one
IUPAC传统名
acetone

产品登记号

EC号 200-662-2
MDL号 MFCD00008765
CAS号 67-64-1
Beilstein号 635680
默克索引号 1466

产品性质

纯度 99+%
沸点 56°C
密度 0.791
闪点 -17°C(1°F)
熔点 -94°C
折射率 1.3590
GHS危险品标识 GHS02
GHS危险品标识 GHS07
GHS危险声明 H225-H319-H336
欧盟危险性物质标志 刺激性(Irritant) 刺激性(Irritant) (Xi)
欧盟危险性物质标志 易燃性(Flammable) 易燃性(Flammable) (F)
GHS警示性声明 P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
危险公开号 11-36-66-67
RTECS编号 AL3150000
安全公开号 9-16-26-46
TSCA收录
联合国危险货物等级 3
联合国危险货物编号 UN1090
联合国危险货物包装类别(PG) II

产品详细信息

参考文献

  • Precursor of dimethyldioxirane, by reaction with K monopersulfate, and isolation in solution by low temperature distillation. For details, see: Chem. Ber., 124, 2377 (1991). It is an excellent reagent for rapid, stereospecific epoxidation of alkenes under mild conditions: J. Org. Chem., 50, 2847 (1985); Org. Synth. Coll., 9, 288 (1998). For improved work-up procedure allowing the possibility of more concentrated solutions or the isolation of acetone-free material, see: Tetrahedron Lett., 37, 3585 (1996). For biphasic, environmentally-friendly system (EtOAc-H2 O), see: Org. Process Res. Dev., 6, 407 (2002). Selective oxidation of phosphorus ylides occurs under mild conditions, providing a route to vicinal tricarbonyl derivatives: J. Org. Chem., 60, 8231 (1995). For conversion of ɑ-bromo-?-dicarbonyls to vicinal tricarbonyls, see: Tetrahedron Lett., 36, 7735 (1995). For formation of singlet oxygen by deoxygenation of heteroaromatic N-oxides, e.g. 4-diethylaminopyridine N-oxide, see: J. Chem. Soc., Chem.Commun., 1831 (1995). For reviews of dioxiranes, see: Acc. Chem. Res., 22, 205 (1989); Chem. Rev., 89, 1187 (1989).