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偶氮二甲酸二异丙酯_分子结构_CAS_2446-83-5)
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偶氮二甲酸二异丙酯

产品号 11626 公司名称 Sigma Aldrich
CAS号 2446-83-5 公司网站 http://www.sigmaaldrich.com
分子式 C8H14N2O4 电 话 1-800-521-8956
分子量 202.20776 传 真
纯 度 ≥94% (GC) 电子邮件
保 存 Chembase数据库ID: 74363

产品价格信息

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产品别名

标题
Diisopropyl azodicarboxylate
IUPAC标准名
N-{[(propan-2-yloxy)carbonyl]imino}(propan-2-yloxy)formamide
IUPAC传统名
diisopropyl azodicarboxylate
别名
Diisopropyl azodiformate
DIAD

产品登记号

EC号 219-502-8
PubChem SID 24847276
MDL号 MFCD00008875
Beilstein号 1912326
CAS号 2446-83-5

产品性质

级别 technical
线性分子式 (CH3)2CHOOCN=NCOOCH(CH3)2
纯度 ≥94% (GC)
沸点 75 °C/0.25 mmHg(lit.)
密度 1.027 g/mL at 25 °C(lit.)
闪点 106 °C
闪点 223 °F
折射率 n20/D 1.420(lit.)
折射率 n20/D 1.420
欧盟危险性物质标志 刺激性(Irritant) 刺激性(Irritant) (Xi)
欧盟危险性物质标志 环境危害性(Nature polluting) 环境危害性(Nature polluting) (N)
MSDS下载 下载链接
RID/ADR UN 3082 9/PG 3
危险公开号 36/38-51/53
安全公开号 26-60
保存温度 2-8°C
联合国危险货物等级 9
联合国危险货物编号 3082
联合国危险货物包装类别(PG) 3
德国WGK号 1

产品详细信息

详细说明 (English)
Other Notes
Reagent used in the Mitsunobu reaction, reviews8,9
Application
Reactant for preparation of:
• Chromenes resembling classical cannabinoids1
• MK-3281 inhibitor of the hepatitis C virus NS5B polymerase2
• Norbornene-based guanidine-rich polymers as mimcs of cell-penetrating peptides (CPP)3
• Analogues of the Pseudomonas aeruginosa quorum-sensing molecule N-(3-Oxododecanoyl)-l-homoserine lactone with immunosuppressive but non-LasR-inducing properties4
• Acceptor-donor-acceptor organic dyes for dye-sensitized solar cells5
• 1,3-dioxane-2-carboxylic acid derivatives as PPARα/γ dual agonists6
• Hydrazinophosphonates and hydrazinobisphosphonates via Mitsunobu and Arbuzov-type multicomponent application of the Morrison-Brunn-Huisgen betaine7
详细说明 (简体中文)
Other Notes
用于 Mitsunobu 反应的试剂,综述8,9
Application
Reactant for preparation of:
• Chromenes resembling classical cannabinoids1
• MK-3281 inhibitor of the hepatitis C virus NS5B polymerase2
• Norbornene-based guanidine-rich polymers as mimcs of cell-penetrating peptides (CPP)3
• Analogues of the Pseudomonas aeruginosa quorum-sensing molecule N-(3-Oxododecanoyl)-l-homoserine lactone with immunosuppressive but non-LasR-inducing properties4
• Acceptor-donor-acceptor organic dyes for dye-sensitized solar cells5
• 1,3-dioxane-2-carboxylic acid derivatives as PPARα/γ dual agonists6
• Hydrazinophosphonates and hydrazinobisphosphonates via Mitsunobu and Arbuzov-type multicomponent application of the Morrison-Brunn-Huisgen betaine7

参考文献