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1-甲酰哌啶

产品号 47725 公司名称 Sigma Aldrich
CAS号 2591-86-8 公司网站 http://www.sigmaaldrich.com
分子式 C6H11NO 电 话 1-800-521-8956
分子量 113.15764 传 真
纯 度 ≥99.0% (GC) 电子邮件
保 存 Chembase数据库ID: 3735

产品价格信息

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产品别名

标题
1-Formylpiperidine
IUPAC标准名
piperidine-1-carbaldehyde
IUPAC传统名
N-formylpiperidine
别名
NFP
Piperidine-1-carboxaldehyde
哌啶-1-甲醛
N-Carbaldehyde piperidine

产品登记号

Beilstein号 107697
MDL号 MFCD00006483
CAS号 2591-86-8
EC号 219-986-0

产品性质

Empirical Formula (Hill Notation) C6H11NO
级别 purum
纯度 ≥99.0% (GC)
沸点 222 °C(lit.)
密度 1.019 g/mL at 25 °C(lit.)
闪点 102 °C
闪点 215.6 °F
折射率 n20/D 1.484(lit.)
折射率 n20/D 1.485
蒸汽压 0.1 mmHg ( 25 °C)
GHS危险品标识 GHS06
GHS警示词 Danger
GHS危险声明 H302-H311-H315-H319-H335
欧盟危险性物质标志 有害性(Harmful) 有害性(Harmful) (Xn)
MSDS下载 下载链接
个人保护装置 Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS警示性声明 P261-P280-P305 + P351 + P338-P312
RID/ADR UN 2810 6.1/PG 3
危险公开号 21/22-36/37/38
RTECS编号 TN0380000
安全公开号 26-36/37
联合国危险货物等级 6.1
联合国危险货物编号 2810
联合国危险货物包装类别(PG) 3
德国WGK号 3

产品详细信息

详细说明 (English)
Other Notes
Used in formyl transfer to Grignard reagents7
Application
Reactant for:
• Direct amidation of azoles with formamides via metal-free C-H activation in the presence of tert-butyl perbenzoate1
• Vilsmeier-type reactions of pyrazoles with amides in the presence of phosphorous oxychloride2
• CO-free aminocarbonylation of N-substituted formamides with aryl iodides/bromides catalyzed by palladium acetate and Xantphos for synthesis of arylamides3
• Synthesis of alternating copolymers for organic photovoltaic applications4
• One-pot double functionalization of π-deficient heterocyclic lithium reagents5
• Synthesis of thermally stable piezofluorochromic aggregation-induced emission compounds6
详细说明 (简体中文)
Other Notes
用于甲酰基转移至格氏试剂的反应7
Application
Reactant for:
• Direct amidation of azoles with formamides via metal-free C-H activation in the presence of tert-butyl perbenzoate1
• Vilsmeier-type reactions of pyrazoles with amides in the presence of phosphorous oxychloride2
• CO-free aminocarbonylation of N-substituted formamides with aryl iodides/bromides catalyzed by palladium acetate and Xantphos for synthesis of arylamides3
• Synthesis of alternating copolymers for organic photovoltaic applications4
• One-pot double functionalization of π-deficient heterocyclic lithium reagents5
• Synthesis of thermally stable piezofluorochromic aggregation-induced emission compounds6

参考文献