三乙基硼 溶液

• 产品号: 90369
• CAS号: 97-94-9
• 分子式: C6H15B
• 分子量: 97.9943

产品别名

• 标题: Triethylborane solution
• IUPAC标准名: triethylborane
• IUPAC传统名: triethylborane

产品登记号

• MDL号: MFCD00009022
• Beilstein号: 1731462
• CAS号: 97-94-9

产品性质

• 浓度: ~15% in hexane
• 级别: purum
• 线性分子式: (C2H5)3B
• 密度: 0.675 g/mL at 20 °C
• 折射率: n20/D 1.380
• GHS警示词: Danger
• GHS危险声明: H250-H261-H302-H304-H314-H336-H361f-H373-H411
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N)
• 个人保护装置: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS警示性声明: P222-P231 + P232-P261-P273-P280-P422
• RID/ADR: UN 3399 4.3/PG 2
• 危险公开号: 17-34-48/20-51/53-62-65-67
• 安全公开号: 26-36/37/39-45-61-62
• 联合国危险货物等级: 4.3
• 联合国危险货物编号: 3399
• 联合国危险货物包装类别(PG): 2
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Catalyst for:
• Allylation of aldehydes1
• Decarboxylative C-C bond cleavage reactions2
• Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations3
• Regioselective hydroxyalkylation of unsaturated oxime ethers4Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes5Reactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential6

详细说明 (简体中文)

Application
Catalyst for:
• Allylation of aldehydes1
• Decarboxylative C-C bond cleavage reactions2
• Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations3
• Regioselective hydroxyalkylation of unsaturated oxime ethers4Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes5Reactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential6