三乙基硅烷

• 产品号: 90550
• CAS号: 617-86-7
• 分子式: C6H16Si
• 分子量: 116.27674
• 纯 度: ≥97.0% (GC)

产品别名

• 标题: Triethylsilane
• IUPAC标准名: triethylsilane
• IUPAC传统名: triethylsilane
• 别名: Triethylhydrosilane; Triethylsilicon hydride; NSC 93579

产品登记号

• Beilstein号: 1098278
• EC号: 210-535-3
• MDL号: MFCD00009018
• CAS号: 617-86-7

产品性质

• 级别: purum
• 线性分子式: (C2H5)3SiH
• 纯度: ≥97.0% (GC)
• 沸点: 107-108 °C(lit.)
• 密度: 0.728 g/mL at 25 °C(lit.)
• 闪点: -3 °C
• 闪点: 26.6 °F
• 折射率: n20/D 1.412(lit.)
• 折射率: n20/D 1.412
• GHS警示词: Danger
• GHS危险声明: H225-H412
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• 个人保护装置: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS警示性声明: P210-P273
• RID/ADR: UN 1993 3/PG 2
• 危险公开号: 11-52/53
• 安全公开号: 9-16-29-33-61
• 联合国危险货物等级: 3
• 联合国危险货物编号: 1993
• 联合国危险货物包装类别(PG): 2
• 德国WGK号: 1

产品详细信息

详细说明 (English)

Other Notes
Reagent for the reduction of various functional groups (e.g. acyl halides to aldehydes, alkyl halides and secondary alcohols to hydrocarbons), review8,9,10; Silylating agent for alcohols, phenols, etc.11,12
Application
Catalyst for:
• Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain1
• Redox initiated cationic polymerization2,3
• Beckmann rearrangement of cyclododecanone oxime4
• Regioselective reductive coupling of enones and allenes5Catalyst reactivation after catalyst polymerization of styrene6Studies involving the prediction of organosilicon flash points7

详细说明 (简体中文)

Other Notes
用于还原各种官能团（如酰基卤还原为醛，烷基卤和仲醇还原为烃）的试剂，综述8,9,10；醇、苯酚等的甲硅烷基化剂。11,12
Application
Catalyst for:
• Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain1
• Redox initiated cationic polymerization2,3
• Beckmann rearrangement of cyclododecanone oxime4
• Regioselective reductive coupling of enones and allenes5Catalyst reactivation after catalyst polymerization of styrene6Studies involving the prediction of organosilicon flash points7