9-硼杂双环[3.3.1]壬基三氟甲磺酸酯 溶液

• 产品号: 15575
• CAS号: 62731-43-5
• 分子式: C9H14BF3O3S
• 分子量: 270.0768696

产品别名

• 标题: 9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution
• IUPAC标准名: (1s,5s)-9-borabicyclo[3.3.1]nonan-9-yl trifluoromethanesulfonate
• IUPAC传统名: (1s,5s)-9-borabicyclo[3.3.1]nonan-9-yl trifluoromethanesulfonate
• 别名: 9-BBN triflate solution; 9-BBN·CF3SO3; 9-[[(Trifluoromethyl)sulfonyl]oxy]-9-borabicyclo[3.3.1]nonane; 9-BBN 三氟甲磺酸酯 溶液

产品登记号

• MDL号: MFCD00167981
• Beilstein号: 995656
• CAS号: 62731-43-5
• PubChem SID: 24849562

产品性质

• 浓度: ~0.5 M in hexane
• Empirical Formula (Hill Notation): C9H14BF3O3S
• 级别: purum
• 闪点: -22 °C
• 闪点: -8 °F
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N)
• RID/ADR: UN 2924 3/PG 2
• 危险公开号: 11-34-48/20-51/53-62-65-67
• 安全公开号: 16-26-36/37/39-45-61-62
• 联合国危险货物等级: 3
• 联合国危险货物编号: 2924
• 联合国危险货物包装类别(PG): 2
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Other Notes
Reagent used for the formation of enol borinates from carbonyl compounds employed in stereoselective aldol reactions7,8,9
Application
Reactant for:
• Preparation of a dialkylborenium ion stabilized by an N-heterocyclic carbene1
• Mukaiyama aldol addition2
• Preparation of porphyrin dimethyldioxanyl tolyl derivative complex3
• Preparation of palladium porphyrin complexes4
• Boron-mediated β-alkoxy Me ketone aldol addition reactions5
• Enolization agent6

详细说明 (简体中文)

Other Notes
用于由羰基化合物形成烯醇硼酸酯（用于不对称羟醛反应）的试剂7,8,9
Application
Reactant for:
• Preparation of a dialkylborenium ion stabilized by an N-heterocyclic carbene1
• Mukaiyama aldol addition2
• Preparation of porphyrin dimethyldioxanyl tolyl derivative complex3
• Preparation of palladium porphyrin complexes4
• Boron-mediated β-alkoxy Me ketone aldol addition reactions5
• Enolization agent6