叔丁氧基双(二甲胺基)甲烷

• 产品号: 20425
• CAS号: 5815-08-7
• 分子式: C9H22N2O
• 分子量: 174.28378

产品别名

• 标题: tert-Butoxy bis(dimethylamino)methane
• IUPAC标准名: [(tert-butoxy)(dimethylamino)methyl]dimethylamine
• IUPAC传统名: [tert-butoxy(dimethylamino)methyl]dimethylamine
• 别名: Bredereck 试剂; Bredereck’s reagent

产品登记号

• MDL号: MFCD00042858
• CAS号: 5815-08-7
• PubChem SID: 24852244
• Beilstein号: 1901973
• EC号: 227-383-9

产品性质

• 级别: technical
• 线性分子式: (CH3)3COCH[N(CH3)2]2
• 沸点: 50-55 °C/15 mmHg(lit.)
• 密度: 0.844 g/mL at 25 °C(lit.)
• 闪点: 41 °C
• 闪点: 105.8 °F
• 折射率: n20/D 1.422(lit.)
• 折射率: n20/D 1.422
• GHS警示词: Warning
• GHS危险声明: H226-H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 个人保护装置: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS警示性声明: P261-P305 + P351 + P338
• RID/ADR: UN 1993 3/PG 3
• 危险公开号: 10-36/37/38
• 安全公开号: 26
• 联合国危险货物等级: 3
• 联合国危险货物编号: 1993
• 联合国危险货物包装类别(PG): 3
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Analysis Note
mixture of tert-Butoxy bis(dimethylamino)methane, tris(dimethylamino)methane and N,N-Dimethylformamide di-tert-butyl acetal
Other Notes
Review5; Mild condensation reactions6
Packaging
10, 50 mL in glass bottle
Application
Reactant for:
• Preparation of pyrroloquinazolines as photochemotherapeutic agents1
• Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereoselective intermolecular radical addition2
• Synthesis of camptothecin via intramolecular isomuenchnone cycloaddition reaction3
• Aminomethylenation reactions4

详细说明 (简体中文)

Analysis Note
叔丁氧基双(二甲胺基)甲烷、三(二甲胺基)甲烷和N,N-二甲基甲酰胺二叔丁基乙缩醛的混合物
Other Notes
综述5；条件温和的缩合反应6
包装
10, 50 mL in glass bottle
Application
Reactant for:
• Preparation of pyrroloquinazolines as photochemotherapeutic agents1
• Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereoselective intermolecular radical addition2
• Synthesis of camptothecin via intramolecular isomuenchnone cycloaddition reaction3
• Aminomethylenation reactions4