N-苯基双(三氟甲烷磺酸亚胺)

• 产品号: 78175
• CAS号: 37595-74-7
• 分子式: C8H5F6NO4S2
• 分子量: 357.2500192
• 纯 度: ≥98.0% (HPLC)

产品别名

• 标题: N-Phenyl-bis(trifluoromethanesulfonimide)
• IUPAC标准名: 1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide
• IUPAC传统名: 1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide
• 别名: 1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide; N-Phenyl-trifluoromethanesulfonimide; 1,1,1-三氟-N-苯基-N-[(三氟甲基)磺酰基]甲磺酰胺; NSC 240874; N,N-Bis(trifluoromethylsulfonyl)aniline; Phenyl triflimide; N,N-双(三氟甲磺酰基)苯胺; N-苯基-三氟甲磺酰亚胺; N-苯基双(三氟甲磺酰)亚胺

产品登记号

• CAS号: 37595-74-7
• MDL号: MFCD00000404
• Beilstein号: 1269141
• PubChem SID: 24887270

产品性质

• 线性分子式: C6H5N(SO2CF3)2
• 纯度: ≥98.0% (HPLC)
• 熔点: 100-102 °C(lit.)
• 熔点: 100-102 °C
• GHS警示词: Warning
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves
• GHS警示性声明: P261-P305 + P351 + P338
• 危险公开号: 36/37/38
• 安全公开号: 26-36
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Other Notes
Stable, crystalline and easy-to-handle triflating agent, useful for the triflation of phenols and amines (especially aliphatic secondary amines; aromatic secondary amines do not react)6; For the preparation of triflones7; For the preparation of enol triflates from ketones8
Packaging
5, 25, 50 g in glass bottle
Application
Acts as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes1Reactant for: Synthesis of amphoteric alpha-boryl aldehydes2 Enantioselective synthesis of core ring skeleton of leucosceptroids A-D3 Stereoselective synthesis of monoamine reuptake inhibitor NS9544 acetate4 Stereoselective sulfoxidation5

详细说明 (简体中文)

Other Notes
稳定、易于处理的晶体状三氟甲磺酸化试剂，可用于酚和胺（尤其是脂族仲胺，但不与芳族仲胺反应）的三氟甲磺酸化6；用于制备三氟甲砜7；用于由酮制备烯醇三氟甲磺酸酯8
包装
5, 25, 50 g in glass bottle
Application
Acts as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes1Reactant for: Synthesis of amphoteric alpha-boryl aldehydes2 Enantioselective synthesis of core ring skeleton of leucosceptroids A-D3 Stereoselective synthesis of monoamine reuptake inhibitor NS9544 acetate4 Stereoselective sulfoxidation5