(乙氧基羰基甲基)三苯基氯化膦

• 产品号: 02615
• CAS号: 17577-28-5
• 分子式: C22H22ClO2P
• 分子量: 384.835641
• 纯 度: ≥90% (AT)

产品别名

• 标题: (Ethoxycarbonylmethyl)triphenylphosphonium chloride
• IUPAC标准名: (2-ethoxy-2-oxoethyl)triphenylphosphanium chloride
• IUPAC传统名: (2-ethoxy-2-oxoethyl)triphenylphosphanium chloride
• 别名: (2-Ethoxy-2-oxoethyl)triphenylphosphonium chloride

产品登记号

• MDL号: MFCD00011746
• PubChem SID: 24845340
• Beilstein号: 3924139
• EC号: 241-548-2
• CAS号: 17577-28-5

产品性质

• 熔点: 120-123 °C(lit.)
• 熔点: 120-123 °C (dec.)
• GHS警示词: Warning
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves
• GHS警示性声明: P261-P305 + P351 + P338
• 危险公开号: 36/37/38
• 安全公开号: 26-36
• 保存温度: 2-8°C
• 德国WGK号: 3
• 级别: technical
• 线性分子式: CH3CH2OCOCH2P(Cl)(C6H5)3
• 纯度: ≥90% (AT)

产品详细信息

详细说明 (English)

Other Notes
Starting material for preparing the Wittig-reagent6,7,8
Application
Reactant for:
• Preparation of disubstituted tetrahydrofurans as selective serotonin re-uptake inhibitors for the treatment of depression1
• Ring-opening reactions with Wittig reagents2
• Enantioselective total synthesis of the phytotoxic lactone herbarumin III via Keck′s asymmetric allylation and Sharpless epoxidation3
• Synthesis of fluorobenzofurans via microwave-assisted tandem intramolecular Wittig and Claisen rearrangement reactions4
• Preparation of phosphonium derivatives of coumarin5

详细说明 (简体中文)

Other Notes
制备 Wittig 试剂的原料6,7,8
Application
Reactant for:
• Preparation of disubstituted tetrahydrofurans as selective serotonin re-uptake inhibitors for the treatment of depression1
• Ring-opening reactions with Wittig reagents2
• Enantioselective total synthesis of the phytotoxic lactone herbarumin III via Keck′s asymmetric allylation and Sharpless epoxidation3
• Synthesis of fluorobenzofurans via microwave-assisted tandem intramolecular Wittig and Claisen rearrangement reactions4
• Preparation of phosphonium derivatives of coumarin5