Grubbs 2 代催化剂

• 产品号: 569747
• CAS号: 246047-72-3
• 分子式: C46H65Cl2N2PRu
• 分子量: 848.971461

产品别名

• 标题: Grubbs Catalyst, 2nd Generation
• IUPAC标准名: [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichloro(phenylmethylidene)ruthenium; tricyclohexylphosphane
• IUPAC传统名: [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichloro(phenylmethylidene)ruthenium; tricyclohexylphosphine
• 别名: 苯亚甲基-1,3-双(2,4,6-三甲苯基)-2-(咪唑啉卡宾)(三环己基磷)二氯化钌; [1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium; Benzylidene[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(tricyclohexylphosphine)ruthenium; 1,3-双(2,4,6-三甲基苯基)-2-(咪唑烷亚基)(二氯苯亚甲基)(三环己基膦)钌; (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium

产品登记号

• CAS号: 246047-72-3
• MDL号: MFCD03453237

产品性质

• Empirical Formula (Hill Notation): C46H65Cl2N2PRu
• 熔点: 143.5-148.5 °C(lit.)
• GHS警示词: Warning
• GHS危险声明: H228
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• 个人保护装置: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• GHS警示性声明: P210
• 危险公开号: 11
• 保存温度: 2-8°C
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
Metathesis: Ruthenium-Based Metathesis CatalystsCatalyst for ring-closing metathesis, cross metathesis and ROMP1 able to produce trisubstituted olefins via cross metathesis,8 and ring closes olefins with excellent functional group tolerance and selectivity.9
Grubbs 2nd Generation CatalystGenerally more active compared to 1st generation catalysts and with a broader substrate scope, including sterically demanding or deactivated olefins such as 1,1-disubstituted olefins and α,β-unsaturated carbonyls.1,2,3,4,5,6,7
Other Notes
NO BULK ORDERS
Packaging
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
US Patent No. 6,111,121 and 7,329,758 (and associated foreign equivalents of the foregoing) apply. Sale of this product conveys to the buyer a limited-use research license. For full details of this license please see sigma-aldrich.com/materialicense. For questions, please contact us at aldrich@sial.com or Materia at info@materia-inc.com.

详细说明 (简体中文)

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
Metathesis: Ruthenium-Based Metathesis CatalystsCatalyst for ring-closing metathesis, cross metathesis and ROMP1 able to produce trisubstituted olefins via cross metathesis,8 and ring closes olefins with excellent functional group tolerance and selectivity.9
Grubbs 2nd Generation CatalystGenerally more active compared to 1st generation catalysts and with a broader substrate scope, including sterically demanding or deactivated olefins such as 1,1-disubstituted olefins and α,β-unsaturated carbonyls.1,2,3,4,5,6,7
Other Notes
不接受批量订单
包装
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
美国专利 6,111,121 和 7,329,758（以及上述专利的相关国外等同专利）均适用。销售该产品可向购买者转让限制使用研究许可。有关该许可的完整详细内容，请访问 sigma-aldrich.com/materialicense。如有疑问，请发送邮件至 aldrich@sial.com 与我们联系，或发送至 info@materia-inc.com 联系 Materia。