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烯丙基硼酸频哪醇酯_分子结构_CAS_72824-04-5)
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烯丙基硼酸频哪醇酯

产品号 324647 公司名称 Sigma Aldrich
CAS号 72824-04-5 公司网站 http://www.sigmaaldrich.com
分子式 C9H17BO2 电 话 1-800-521-8956
分子量 168.04108 传 真
纯 度 97% 电子邮件
保 存 Chembase数据库ID: 63858

产品价格信息

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产品别名

标题
Allylboronic acid pinacol ester
IUPAC标准名
4,4,5,5-tetramethyl-2-(prop-2-en-1-yl)-1,3,2-dioxaborolane
IUPAC传统名
4,4,5,5-tetramethyl-2-(prop-2-en-1-yl)-1,3,2-dioxaborolane
别名
Pinacol allylboronate
Pinacolyl 2-propenylboronate
4,4,5,5-tetramethyl-2-(2-propenyl)-1,3,2-dioxaborolane
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
4,4,5,5-tetramethyl-2-(2-propen-1-yl)-1,3,2-dioxaborolane
Allyl pinacol boronate
2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧环戊硼烷
丙烯基硼酸频哪醇酯

产品登记号

PubChem SID 24859457
MDL号 MFCD00013347
CAS号 72824-04-5

产品性质

线性分子式 ((CH3)4C2O2)BCH2CH=CH2
纯度 97%
沸点 50-53 °C/5 mmHg(lit.)
密度 0.896 g/mL at 25 °C(lit.)
闪点 46 °C
闪点 114.8 °F
折射率 n20/D 1.4268(lit.)
GHS危险品标识 GHS02
GHS危险品标识 GHS07
GHS警示词 Warning
GHS危险声明 H226-H315-H319-H335
欧盟危险性物质标志 刺激性(Irritant) 刺激性(Irritant) (Xi)
MSDS下载 下载链接
个人保护装置 Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS警示性声明 P261-P305 + P351 + P338
RID/ADR UN 1993 3/PG 3
危险公开号 10-36/37/38
安全公开号 26-36
保存温度 2-8°C
联合国危险货物等级 3
联合国危险货物编号 1993
联合国危险货物包装类别(PG) 3
德国WGK号 3

产品详细信息

详细说明 (English)
Packaging
1, 10 g in glass bottle
Application
Reagent used for
• Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis1
• Intermolecular radical additions2
• Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids3
• Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes4
• Nucleic acid-templated energy transfer leading to a photorelease reaction5
• Stereoselective indium-catalyzed Hosomi-Sakurai reactions6 Reagent used in Preparation of
• Cyclic sulfone hydroxyethylamines as BACE1 inhibitors for reduction of Amyloid β-Peptides7
• Transmetalation of carbene Ru iodide with Ag carboxylates to give C-H-activated Ru carbene complexes as catalysts for Z-selective olefin metathesis8
详细说明 (简体中文)
包装
1, 10 g in glass bottle
Application
Reagent used for
• Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis1
• Intermolecular radical additions2
• Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids3
• Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes4
• Nucleic acid-templated energy transfer leading to a photorelease reaction5
• Stereoselective indium-catalyzed Hosomi-Sakurai reactions6 Reagent used in Preparation of
• Cyclic sulfone hydroxyethylamines as BACE1 inhibitors for reduction of Amyloid β-Peptides7
• Transmetalation of carbene Ru iodide with Ag carboxylates to give C-H-activated Ru carbene complexes as catalysts for Z-selective olefin metathesis8

参考文献