1,1′-双(苯基亚膦基)二茂铁

• 产品号: 567159
• CAS号: 72954-06-4
• 分子式: C16H13FeP
• 分子量: 292.093181
• 纯 度: 97%

产品别名

• 标题: 1,1′-Bis(phenylphosphinidene)ferrocene
• IUPAC标准名: λ^2-iron(2+) ion 3-[cyclopenta-1,4-dien-3-id-1-yl(phenyl)phosphanyl]cyclopenta-2,4-dien-1-ide
• IUPAC传统名: λ^2-iron(2+) ion 3-[cyclopenta-1,4-dien-3-id-1-yl(phenyl)phosphanyl]cyclopenta-2,4-dien-1-ide
• 别名: 1,1′-(Ferrocenediyl)phenylphosphine; 1,1′-(二茂铁二基)苯膦

产品登记号

• CAS号: 72954-06-4
• PubChem SID: 24880349
• MDL号: MFCD04974069

产品性质

• 线性分子式: C5H4PC6H5C5H4Fe
• 纯度: 97%
• 熔点: 88-92 °C(lit.)
• 个人保护装置: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• 保存温度: 2-8°C
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Packaging
1 g in glass bottle
Application
Reactant for:
• Preparation of macrocyclic tridentate ferrocenylphosphine ligands1
• Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations2
• Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes3
• Ring-opening reactions via ring slippage4
• Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate5

详细说明 (简体中文)

包装
1 g in glass bottle
Application
Reactant for:
• Preparation of macrocyclic tridentate ferrocenylphosphine ligands1
• Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations2
• Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes3
• Ring-opening reactions via ring slippage4
• Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate5