(R)-(+)-2-甲基-2-丙烷亚磺酰胺

• 产品号: 497401
• CAS号: 196929-78-9
• 分子式: C4H11NOS
• 分子量: 121.20124
• 纯 度: 98%

产品别名

• 标题: (R)-(+)-2-Methyl-2-propanesulfinamide
• IUPAC标准名: (R)-2-methylpropane-2-sulfinamide
• IUPAC传统名: (R)-2-methylpropane-2-sulfinamide

产品登记号

• MDL号: MFCD05861479
• CAS号: 196929-78-9
• PubChem SID: 24873117

产品性质

• 线性分子式: (CH3)3CS(O)NH2
• 纯度: 98%
• 熔点: 103-107 °C(lit.)
• 比旋光度: [α]20/D +4°, c = 1.0242 in chloroform stab. with amylenes
• 个人保护装置: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• 保存温度: 2-8°C
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Can be readily transformed into P,N-sulfinyl imine ligands through condensation with aldehydes and ketones, which can undergo iridium-catalyzed asymmetric hydrogenation of olefins.1
Preparation of β-chloro sulfinamides in a synthesis of chiral azridines. Also used to prepare an organocatalyst for enantioselective reduction of imines.
Useful reagent for synthesizing chiral amines.
Ellman′s Sulfinamides
Packaging
1, 5 g in glass bottle
25 g in poly bottle

详细说明 (简体中文)

Application
合成手性胺的有效试剂。
在手性氮丙啶的合成中制备 β-氯代亚磺酰胺。也可用于制备亚胺对映选择性还原反应的有机催化剂。
易与醛和酮发生缩合反应，转化为 P,N-亚磺酰亚胺配体，该配体可参与烯烃的铱催化不对称氢化反应。1
Ellman′s Sulfinamides
包装
1, 5 g in glass bottle
25 g in poly bottle