三(三苯基膦)氯化铑(I)

• 产品号: 205036
• CAS号: 14694-95-2
• 分子式: C54H45ClP3Rh
• 分子量: 925.214883
• 纯 度: 99.9% trace metals basis

产品别名

• 标题: Tris(triphenylphosphine)rhodium(I) chloride
• IUPAC标准名: chlororhodium; tris(triphenylphosphane)
• IUPAC传统名: chlororhodium; tris(triphenylphosphine)
• 别名: Wilkinson 催化剂; RhCl(PPh3)3; Wilkinson’s catalyst; NSC 124140; Rhodium(I) tris(triphenylphosphine) chloride; 三(三苯膦基)氯化铑(I)

产品登记号

• Beilstein号: 4581440
• MDL号: MFCD00010016
• PubChem SID: 24852305
• EC号: 238-744-5
• CAS号: 14694-95-2

产品性质

• 线性分子式: [(C6H5)3P]3RhCl
• 纯度: 99.9% trace metals basis
• 个人保护装置: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Useful catalyst for the efficient cross-coupling of activated alkenyl tosylates with arylboronic acids.6 Also used to catalyze the cleavage of allyl phenolic ethers to phenols with DABCO.7
Hydrosilylation CatalystsCatalyst used for many organic reactions including:
• Chemoselective allylic alkylations1
• Stoichiometric activation of Si-H bonds2 and hydrosilylations3
• Inter- and intramolecular hydroacylation of alkenes along with a cocatalyst4
• Polymerization of diorganostannanes5
Packaging
1 g in glass bottle
250 mg in glass bottle
5 g in poly bottle

详细说明 (简体中文)

Application
用于芳基硼酸与活化的烯基甲苯磺酸酯进行交叉偶联反应的有效催化剂。6也用于催化 DABCO 作用下烯丙基酚醚裂解为酚。7
Hydrosilylation CatalystsCatalyst used for many organic reactions including:
• Chemoselective allylic alkylations1
• Stoichiometric activation of Si-H bonds2 and hydrosilylations3
• Inter- and intramolecular hydroacylation of alkenes along with a cocatalyst4
• Polymerization of diorganostannanes5
包装
1 g in glass bottle
250 mg in glass bottle
5 g in poly bottle