Packaging
1, 5 g in glass bottle
250 mg in glass bottle
Application
2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl and its rhodium and ruthenium derivatives are highly selective homogeneous catalysts used for the reduction of aryl ketones,1 β-keto esters,2 and α-amino ketones.3 They have also been used for asymmetric hydrogenation4 and hydroformylation of olefins,5 asymmetric Heck reactions,6 and asymmetric isomerizations of allyls.7,8Ligand used in a palladium-catalyzed, asymmetric, tandem Heck reaction-carbanion capture process leading to a synthesis of a tricyclic sesquiterpene. Also used in a ruthenium-catalyzed asymmetric hydrogenation of α,β-unsaturated acids.
Reactant involved in:
• Enantioselective and diastereoselective unpoled carbonyl allylation
• Syntehsis of organophophine oxides as anittumor agents
• SN2 halogenation of hydroxy groups
• Synthesis of BINAP complexes
• Studies of conformational flexibility of BINAP chelates |
包装
1, 5 g in glass bottle
250 mg in glass bottle
Application
2,2′-双(二苯基膦)-1,1′-联萘及其铑和钌衍生物可作为高选择性均相催化剂，用于芳基酮、1β-酮酸酯2和 α-氨基酮的还原反应。3也可用于烯烃的不对称氢化4和氢甲酰化反应、5不对称 Heck 反应6和烯丙基的不对称异构化反应。7,8 用于钯催化不对称串联 Heck 反应的配体，这种碳负离子捕获过程可合成三环倍半萜烯。也可用于钌催化的 α,β-不饱和酸的不对称氢化反应。
Reactant involved in:
• Enantioselective and diastereoselective unpoled carbonyl allylation
• Syntehsis of organophophine oxides as anittumor agents
• SN2 halogenation of hydroxy groups
• Synthesis of BINAP complexes
• Studies of conformational flexibility of BINAP chelates |