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氯二(环辛烯)铱(I)二聚体_分子结构_CAS_12246-51-4)
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氯二(环辛烯)铱(I)二聚体

产品号 377155 公司名称 Sigma Aldrich
CAS号 12246-51-4 公司网站 http://www.sigmaaldrich.com
分子式 C32H56Cl2Ir2 电 话 1-800-521-8956
分子量 896.12704 传 真
纯 度 97% 电子邮件
保 存 Chembase数据库ID: 148033

产品价格信息

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产品别名

标题
Chlorobis(cyclooctene)iridium(I)dimer
IUPAC标准名
tetrakis((Z)-cyclooctene); bis(chloroiridium)
IUPAC传统名
bis(chloroiridium); tetrakis(cyclooctene)
别名
二-μ-氯四(环辛烯)二铱
Di-μ-chlorotetrakis(cyclooctene)diiridium

产品登记号

CAS号 12246-51-4
MDL号 MFCD00213465
PubChem SID 24863496

产品性质

Empirical Formula (Hill Notation) C32H56Cl2Ir2
纯度 97%
熔点 160-165 °C (dec.)(lit.)
GHS危险品标识 GHS07
GHS警示词 Warning
GHS危险声明 H315-H319-H335
欧盟危险性物质标志 刺激性(Irritant) 刺激性(Irritant) (Xi)
MSDS下载 下载链接
个人保护装置 dust mask type N95 (US), Eyeshields, Gloves
GHS警示性声明 P261-P305 + P351 + P338
危险公开号 36/37/38
安全公开号 26-37/39
德国WGK号 3

产品详细信息

详细说明 (English)
Packaging
1, 5 g in glass bottle
250 mg in glass bottle
Application
Catalyst for:
• Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand1
• Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions2
• Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions3
• Alkylation reactions4
• Guerbet reaction5
• Allylic amination reactions in a DNA-diene-iridium(I) hybrid system6
• Asymmetric hydroamination reactions7
详细说明 (简体中文)
包装
1, 5 g in glass bottle
250 mg in glass bottle
Application
Catalyst for:
• Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand1
• Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions2
• Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions3
• Alkylation reactions4
• Guerbet reaction5
• Allylic amination reactions in a DNA-diene-iridium(I) hybrid system6
• Asymmetric hydroamination reactions7

参考文献