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(R,R)-(-)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺_分子结构_CAS_135616-40-9)
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(R,R)-(-)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺

产品号 404411 公司名称 Sigma Aldrich
CAS号 135616-40-9 公司网站 http://www.sigmaaldrich.com
分子式 C36H54N2O2 电 话 1-800-521-8956
分子量 546.82616 传 真
纯 度 98% 电子邮件
保 存 Chembase数据库ID: 147709

产品价格信息

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产品别名

标题
(R,R)-(-)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
IUPAC标准名
2,4-di-tert-butyl-6-{N-[(1R,2R)-2-{[(3,5-di-tert-butyl-2-hydroxyphenyl)methylidene]amino}cyclohexyl]carboximidoyl}phenol
IUPAC传统名
2,4-di-tert-butyl-6-{N-[(1R,2R)-2-{[(3,5-di-tert-butyl-2-hydroxyphenyl)methylidene]amino}cyclohexyl]carboximidoyl}phenol
别名
(R,R)-Jacobsen 配体
(R,R)-Jacobsen’s ligand

产品登记号

MDL号 MFCD00191800
PubChem SID 24865244
CAS号 135616-40-9
Beilstein号 5464823

产品性质

线性分子式 [[(CH3)3C]2C6H2-2-(OH)CH=N]2C6H10
纯度 98%
熔点 205-207 °C(lit.)
比旋光度 [α]20/D -315±15°, c = 1 in methylene chloride
GHS危险品标识 GHS07
GHS警示词 Warning
GHS危险声明 H315-H319-H335
欧盟危险性物质标志 刺激性(Irritant) 刺激性(Irritant) (Xi)
MSDS下载 下载链接
个人保护装置 dust mask type N95 (US), Eyeshields, Gloves
GHS警示性声明 P261-P305 + P351 + P338
危险公开号 36/37/38
安全公开号 26
德国WGK号 3

产品详细信息

详细说明 (English)
Biochem/physiol Actions
Lipases catalyze the hydrolysis of triacylglycerols into glycerol and free fatty acids.
α-amylase catalyzes the hydrolysis of internal α-1,4-O-glycosidic bonds in starches to release α-anomeric sugars.2
Packaging
1, 5 g in glass bottle
Legal Information
Manufactured under license by Shasun Chemicals and Drugs Limited, using Jacobsen HKR technology.
Application
Amylases from Aspergillus oryzae are used to prevent staling in the baking industry, clarify haze from fruit juices and alcoholic beverages, and produce glucose and maltose syrup products.1
Versatile ligand for asymmetric catalysis. Ligand used for preparing Jacobsen′s catalyst suitable for enantioselective epoxidation of olefins lacking functional groups.Lipases are used industrially for the resolution of chiral compounds and the transesterification production of biodiesel.
详细说明 (简体中文)
Biochem/physiol Actions
Lipases catalyze the hydrolysis of triacylglycerols into glycerol and free fatty acids.
α-amylase catalyzes the hydrolysis of internal α-1,4-O-glycosidic bonds in starches to release α-anomeric sugars.2
包装
1, 5 g in glass bottle
Legal Information
经 Shasun Chemicals and Drugs Limited 授权,使用 Jacobsen HKR 技术制造。
Application
Amylases from Aspergillus oryzae are used to prevent staling in the baking industry, clarify haze from fruit juices and alcoholic beverages, and produce glucose and maltose syrup products.1
Versatile ligand for asymmetric catalysis. Ligand used for preparing Jacobsen′s catalyst suitable for enantioselective epoxidation of olefins lacking functional groups.Lipases are used industrially for the resolution of chiral compounds and the transesterification production of biodiesel.

参考文献