硼烷二甲基硫醚络合物 溶液

• 产品号: 192120
• CAS号: 13292-87-0
• 分子式: C2H9BS
• 分子量: 75.96886

产品别名

• 标题: Borane dimethyl sulfide complex solution
• IUPAC标准名: (methylsulfanyl)methane borane
• IUPAC传统名: dimethyl sulfide borane
• 别名: BMS; Trihydro[thiobis[methane]]boron

产品登记号

• PubChem SID: 24851530
• Beilstein号: 3663489
• MDL号: MFCD00013189
• CAS号: 13292-87-0

产品性质

• 个人保护装置: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS警示性声明: P210-P223-P231 + P232-P261-P370 + P378-P422
• RID/ADR: UN 3399 4.3/PG 1
• 危险公开号: 11-14/15-19-37-41
• 安全公开号: 16-26-39-43
• GHS警示词: Danger
• GHS危险声明: H225-H260-H315-H318-H335
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 保存温度: 2-8°C
• 欧盟补充危害声明: May form explosive peroxides., Reacts violently with water.
• 联合国危险货物等级: 4.3
• 联合国危险货物编号: 3399
• 联合国危险货物包装类别(PG): 1
• 德国WGK号: 3
• 浓度: 2.0 M in THF
• 线性分子式: (CH3)2S · BH3
• 密度: 0.855 g/mL at 25 °C
• 闪点: -17 °C
• 闪点: 1.4 °F

产品详细信息

详细说明 (English)

Application
Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.6 CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to chiral 1,3-diols.7 Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.8
Reactant used as a regioselective reducing agent1,2Reactant involved in:
• Hydroboration / oxidation3,4Synthesis of cage compounds5
Packaging
100, 800 mL in Sure/Seal™

详细说明 (简体中文)

Application
与树枝状聚合物负载的 L-吡咯烷醇共同用于茚酮和四氢萘酮的不对称还原反应。6二茂铁基-1,3-二酮转化为手性 1,3-二醇的 CBS 催化不对称还原反应。7C3-对称三脚羟基酰胺催化的酮高度不对称还原反应。8
Reactant used as a regioselective reducing agent1,2Reactant involved in:
• Hydroboration / oxidation3,4Synthesis of cage compounds5
包装
100, 800 mL in Sure/Seal™