(+)-B-甲氧基二异松蒎基硼烷

• 产品号: 317039
• CAS号: 99438-28-5
• 分子式: C21H37BO
• 分子量: 316.32888

产品别名

• 标题: (+)-B-Methoxydiisopinocampheylborane
• IUPAC标准名: methyl bis[(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl]borinate
• IUPAC传统名: methyl bis(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ylborinate
• 别名: (+)-二异松蒎基甲氧基硼烷; (+)-Diisopinocampheylmethoxyborane

产品登记号

• PubChem SID: 24859061
• CAS号: 99438-28-5
• Beilstein号: 6370228
• MDL号: MFCD21332906

产品性质

• Empirical Formula (Hill Notation): C21H37BO
• 闪点: 113 °C
• 闪点: 235.4 °F
• GHS警示词: Warning
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves
• GHS警示性声明: P261-P305 + P351 + P338
• 危险公开号: 36/37/38
• 安全公开号: 26-36
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Both (+)- and (-)-forms are precursors to B-allyldiisopinocampheylborane derivatives, which are subsequently reacted with aldehydes to give homoallylic alcohols6 and β-amino alcohols7 of high enantiomeric excess.8
Reactant involved in:
• Oxidative cyclization and alkylation for synthesis of ionomycin1
• Intramolecular conjugate addition for tetrahydropyran synthesis2
• Aldol addition and Suzuki coupling reactions3
• Allylation4
• Synthesis of alkanols5
Packaging
5, 25, 100 g in glass bottle

详细说明 (简体中文)

Application
(+)- 和 (-)- 形式均为 B-烯丙基二异松蒎基硼烷衍生物的前体，这两种形式随后与醛反应生成具有高光学纯度的高烯丙醇6 和 β-氨基醇7。8
Reactant involved in:
• Oxidative cyclization and alkylation for synthesis of ionomycin1
• Intramolecular conjugate addition for tetrahydropyran synthesis2
• Aldol addition and Suzuki coupling reactions3
• Allylation4
• Synthesis of alkanols5
包装
5, 25, 100 g in glass bottle