N-甲氧基-N-甲羰基甲基膦酸二乙酯

• 产品号: 362433
• CAS号: 124931-12-0
• 分子式: C8H18NO5P
• 分子量: 239.205981
• 纯 度: 96%

产品别名

• 标题: Diethyl (N-methoxy-N-methylcarbamoylmethyl)phosphonate
• IUPAC标准名: diethyl {[methoxy(methyl)carbamoyl]methyl}phosphonate
• IUPAC传统名: diethyl [methoxy(methyl)carbamoyl]methylphosphonate
• 别名: Diethylphosphonoacetic acid N-methyl-N-methoxyamide; N-Methoxy-N-methyl-2-(diethyl phosphono)acetamide; Diethyl N-methoxy-N-methylphosphonoacetamide; N-Methoxy-N-methyl-phosphonoacetamide diethyl ester

产品登记号

• MDL号: MFCD00134233
• CAS号: 124931-12-0
• Beilstein号: 1875865
• PubChem SID: 24862312

产品性质

• 线性分子式: CH3ON(CH3)COCH2P(O)(OC2H5)2
• 纯度: 96%
• 沸点: 90 °C/17 mmHg(lit.)
• 密度: 1.163 g/mL at 25 °C(lit.)
• 闪点: 110 °C
• 闪点: 230 °F
• 折射率: n20/D 1.455(lit.)
• GHS警示词: Warning
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 个人保护装置: Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS警示性声明: P261-P305 + P351 + P338
• 危险公开号: 36/37/38
• 安全公开号: 26-36
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Wittig carbonylating reagent.7
Reactant for:
• Preparation of ring-expanded bryostatin analogs as antitumor agents1
• Asymmertic synthesis of pinnatoxins A and G via diastereoselective Ireland-Claisen rearrangement, ring closing metathesis, and cyclization2
• Rh2(II)-catalyzed nitro-group migration reactions3
• Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition reactions4
• Stereoselective synthesis of (+)-polyrhacitide A via aldol reaction, Horner-Wardsworth-Emmons reaction, Evans acetal intramolecular oxa-Michael reaction and diastereoselective syn reduction reaction as the key steps5
• Preparation of substituted furans via olefin cross-metathesis6
Packaging
1, 5 g in glass bottle

详细说明 (简体中文)

Application
Wittig 羰基化试剂7
Reactant for:
• Preparation of ring-expanded bryostatin analogs as antitumor agents1
• Asymmertic synthesis of pinnatoxins A and G via diastereoselective Ireland-Claisen rearrangement, ring closing metathesis, and cyclization2
• Rh2(II)-catalyzed nitro-group migration reactions3
• Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition reactions4
• Stereoselective synthesis of (+)-polyrhacitide A via aldol reaction, Horner-Wardsworth-Emmons reaction, Evans acetal intramolecular oxa-Michael reaction and diastereoselective syn reduction reaction as the key steps5
• Preparation of substituted furans via olefin cross-metathesis6
包装
1, 5 g in glass bottle