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三(二亚苄基丙酮)二钯(0)_分子结构_CAS_51364-51-3)
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三(二亚苄基丙酮)二钯(0)

产品号 328774 公司名称 Sigma Aldrich
CAS号 51364-51-3 公司网站 http://www.sigmaaldrich.com
分子式 C51H42O3Pd2 电 话 1-800-521-8956
分子量 915.71738 传 真
纯 度 97% 电子邮件
保 存 Chembase数据库ID: 70002

产品价格信息

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产品别名

标题
Tris(dibenzylideneacetone)dipalladium(0)
IUPAC标准名
tris(1,5-diphenylpenta-1,4-dien-3-one) dipalladium
IUPAC传统名
tris(dibenzylideneacetone) dipalladium
别名
Pd2(dba)3
Pd2dba3

产品登记号

PubChem SID 24859746
CAS号 51364-51-3
MDL号 MFCD00013310

产品性质

线性分子式 (C6H5CH=CHCOCH=CHC6H5)3Pd2
纯度 97%
熔点 152-155 °C(lit.)
MSDS下载 下载链接
个人保护装置 Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
德国WGK号 2

产品详细信息

详细说明 (English)
Packaging
1, 5, 25, 50, 100 g in glass bottle
500 mg in glass bottle
Application

• Catalyst for Suzuki coupling of aryl chlorides (eq. 1)
• Catalyst for Heck coupling of aryl chlorides (eq. 2)
• Catalyst for arylation of ketones (eq. 3)
• Catalyst for Buchwald-Hartwig amination of aryl halides (eq. 4)
• Catalyst for fluorination of allylic chlorides (eq. 5)
• Catalyst for β-arylation of carboxylic esters (eq. 6)
• Catalyst for carbonylation of 1,1-dichloro-1-alkenes (eq. 7)
• Catalyst for conversion of aryl and vinyl triflates to aryl and vinyl halides (eq. 8)
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsReactant involved in:
• Synthesis of nanosized palladium phosphides upon interaction with white phosphorous1
• Preparation of palladium triphenylphosphine carbonyl cluster complexes2
• Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions3
• Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynes4Catalyst for:
• Suzuki cross-coupling reactions5
• PCN- and PCS-pincer palladium complex catalyzed tandem allylation6
详细说明 (简体中文)
包装
1, 5, 25, 50, 100 g in glass bottle
500 mg in glass bottle
Application

• Catalyst for Suzuki coupling of aryl chlorides (eq. 1)
• Catalyst for Heck coupling of aryl chlorides (eq. 2)
• Catalyst for arylation of ketones (eq. 3)
• Catalyst for Buchwald-Hartwig amination of aryl halides (eq. 4)
• Catalyst for fluorination of allylic chlorides (eq. 5)
• Catalyst for β-arylation of carboxylic esters (eq. 6)
• Catalyst for carbonylation of 1,1-dichloro-1-alkenes (eq. 7)
• Catalyst for conversion of aryl and vinyl triflates to aryl and vinyl halides (eq. 8)
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsReactant involved in:
• Synthesis of nanosized palladium phosphides upon interaction with white phosphorous1
• Preparation of palladium triphenylphosphine carbonyl cluster complexes2
• Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions3
• Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynes4Catalyst for:
• Suzuki cross-coupling reactions5
• PCN- and PCS-pincer palladium complex catalyzed tandem allylation6

参考文献