(1S,2S)-N,N′-双(2-乙酰-3-氧代-2-亚丁烯基)-1,2-二均三甲苯基乙二胺合钴(II)

• 产品号: 708844
• CAS号: 259259-80-8
• 分子式: C32H38CoN2O4
• 分子量: 573.58832

产品别名

• 标题: (1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
• IUPAC标准名: 1-[(8S,9S)-12-acetyl-4,13-dimethyl-8,9-bis(2,4,6-trimethylphenyl)-1,3-dioxa-7,10-diaza-2-cobaltacyclotrideca-4,6,10,12-tetraen-5-yl]ethan-1-one
• IUPAC传统名: 1-[(8S,9S)-12-acetyl-4,13-dimethyl-8,9-bis(2,4,6-trimethylphenyl)-1,3-dioxa-7,10-diaza-2-cobaltacyclotrideca-4,6,10,12-tetraen-5-yl]ethanone
• 别名: (S,S)-AMAC

产品登记号

• MDL号: MFCD06797062
• CAS号: 259259-80-8

产品性质

• Empirical Formula (Hill Notation): C32H38CoN2O4
• 熔点: 242-246 °C
• 比旋光度: [α]/D -309°, c = 0.1 in chloroform
• 个人保护装置: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Packaging
100, 500 mg in glass bottle
Application
Catalyst for:
• Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene1
• Enantioselective borohydride reduction2
• Preparation of β-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases3
• Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones4

详细说明 (简体中文)

包装
100, 500 mg in glass bottle
Application
Catalyst for:
• Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene1
• Enantioselective borohydride reduction2
• Preparation of β-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases3
• Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones4