[(R)-(+)-2,2′-双(二-对甲苯基膦)-1,1′-联萘]氯化钯(II)

• 产品号: 708461
• CAS号: 191654-69-0
• 分子式: C48H40Cl2P2Pd
• 分子量: 856.104722

产品别名

• 标题: [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride
• IUPAC标准名: (1-{2-[bis(4-methylphenyl)phosphanyl]naphthalen-1-yl}naphthalen-2-yl)bis(4-methylphenyl)phosphane; dichloropalladium
• IUPAC传统名: (1-{2-[bis(4-methylphenyl)phosphanyl]naphthalen-1-yl}naphthalen-2-yl)bis(4-methylphenyl)phosphane; palladium chloride
• 别名: [PdCl2{(R)-4-tolylbinap}]

产品登记号

• CAS号: 191654-69-0
• MDL号: MFCD11656205

产品性质

• Empirical Formula (Hill Notation): C48H40Cl2P2Pd
• 熔点: >300 °C
• GHS警示词: Warning
• GHS危险声明: H302 + H312 + H332-H315-H319-H335
• 欧盟危险性物质标志: 有害性(Harmful) (Xn)
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves
• GHS警示性声明: P261-P280-P305 + P351 + P338
• 危险公开号: 20/21/22-36/37/38
• 安全公开号: 26
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Packaging
100, 500 mg in glass bottle
Application
Catalyst for:
• Enantioselective preparation of hydroxydicarbonyls via aldol addition of pyruvates and diketones with ketene thioacetal1
• Stereoselective aldol condensation using trimethyl[[(phenyl)ethenyl]oxy]silane and benzaldehyde as reactants2
• Stereoselective preparation of naphthalenols via alkylative ring opening of oxabenzonorbornadienes with dialkylzinc3Reactant for:
• Preparation of palladium bis(diphenylphosphino)binaphthyl aqua mononuclear and hydroxo-bridged dinuclear complexes4

详细说明 (简体中文)

包装
100, 500 mg in glass bottle
Application
Catalyst for:
• Enantioselective preparation of hydroxydicarbonyls via aldol addition of pyruvates and diketones with ketene thioacetal1
• Stereoselective aldol condensation using trimethyl[[(phenyl)ethenyl]oxy]silane and benzaldehyde as reactants2
• Stereoselective preparation of naphthalenols via alkylative ring opening of oxabenzonorbornadienes with dialkylzinc3Reactant for:
• Preparation of palladium bis(diphenylphosphino)binaphthyl aqua mononuclear and hydroxo-bridged dinuclear complexes4