(S,S′,R,R′)-TangPhos-铑络合物

• 产品号: 659703
• 分子式: C24H44BF4P2Rh
• 分子量: 584.2637948

产品别名

• 标题: (S,S′,R,R′)-TangPhos-rhodium complex
• IUPAC标准名: λ^1-rhodium(1+) ion (2R)-1-tert-butyl-2-[(2R)-1-tert-butylphospholan-2-yl]phospholane cycloocta-1,5-diene tetrafluoroboranuide
• IUPAC传统名: λ^1-rhodium(1+) ion (2R)-1-tert-butyl-2-[(2R)-1-tert-butylphospholan-2-yl]phospholane 1,5-cyclooctadiene tetrafluoroborate
• 别名: (S,S′,R,R′)-TangPhos(环辛二烯)四氟硼酸铑(I); (S,S′,R,R′)-TangPhos(cyclooctadiene)rhodium(I) tetrafluoroborate

产品登记号

• MDL号: MFCD07782006
• PubChem SID: 24884438

产品性质

• Empirical Formula (Hill Notation): C24H44BF4P2Rh
• 熔点: >300 °C
• 个人保护装置: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Highly efficient in rhodium-catalyzed hydrogenation of α-dehyroamino acids and α-arylenamides,1 β-(acylamino)acrylates,2 itaconic acids, and enol acetates.3 Also gives outstanding enantioselectivities in asymmetric hydroformylation reactions.4
Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
Packaging
100, 500 mg in glass bottle

详细说明 (简体中文)

Application
在 α-脱氢氨基酸、α-芳基烯酰胺、1β-(酰胺基)丙烯酸酯、2衣康酸以及乙酸烯醇酯的铑催化氢化中具有高效性。3也能在不对称加氢甲酰化反应中提供出色的对映选择性。4
Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
包装
100, 500 mg in glass bottle