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二氯(三环己基膦)[(三环己基正膦基)亚甲基]四氟硼酸钌(II)_分子结构_CAS_1020085-61-3)
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二氯(三环己基膦)[(三环己基正膦基)亚甲基]四氟硼酸钌(II)

产品号 707961 公司名称 Sigma Aldrich
CAS号 1020085-61-3 公司网站 http://www.sigmaaldrich.com
分子式 C37H67BCl2F4P2Ru 电 话 1-800-521-8956
分子量 832.6560148 传 真
纯 度 95% 电子邮件
保 存 Chembase数据库ID: 142530

产品价格信息

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产品别名

标题
Dichloro(tricyclohexylphosphine)[(tricyclohexylphosphoranyl)methylidene]ruthenium(II) tetrafluoroborate
IUPAC标准名
tetrafluoroboranuide; tricyclohexyl[(dichlororutheniumylidene)methyl]phosphanium; tricyclohexylphosphane
IUPAC传统名
tricyclohexyl[(dichlororutheniumylidene)methyl]phosphanium tricyclohexylphosphine tetrafluoroborate
别名
Piers first generation metathesis catalyst
Dichloro(PCy3)[(tricyclohexylphosphoranyl)methylidene]Ru tetrafluoroborate
Piers 第一代复分解反应催化剂

产品登记号

MDL号 MFCD15144782
CAS号 1020085-61-3

产品性质

Empirical Formula (Hill Notation) C37H67BCl2F4P2Ru
纯度 95%
熔点 203 °C (dec.)
GHS危险品标识 GHS02
GHS警示词 Warning
GHS危险声明 H228
欧盟危险性物质标志 易燃性(Flammable) 易燃性(Flammable) (F)
MSDS下载 下载链接
个人保护装置 Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
GHS警示性声明 P210
危险公开号 11
保存温度 2-8°C
德国WGK号 1

产品详细信息

详细说明 (English)
Other Notes
No bulk orders
Packaging
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
US Patent No. 7,365,140 (and associated foreign equivalents) owned by UTI Limited Partnership and licensed to Materia; Inc. apply. Sale of this product conveys to the buyer a limited-use research license. For full details of this license please see sigma-aldrich.com/materialicense. For questions; please contact us at aldrich@sial.com or Materia at info@materia-inc.com.
Application

• Cationic 4-coordinate catalyst is considered “pre-activated” because no ligand dissociation is required for formation of the active catalytic species.
• Has reactivity profile similar to the Grubbs 1st Generation Catalyst but is active at much lower temperatures (below 0 °C).1
详细说明 (简体中文)
Other Notes
不接受批量订单
包装
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
美国专利号 7,365,140(和相关国外等同专利)归 UTI Limited Partnership 所有,授权 Materia; Inc. 使用。销售该产品可向购买者转让限制使用研究许可。有关该许可的完整详细内容,请访问 sigma-aldrich.com/materialicense。如有疑问;请发送邮件至 aldrich@sial.com 与我们联系,或发送至 info@materia-inc.com 联系 Materia。
Application

• Cationic 4-coordinate catalyst is considered “pre-activated” because no ligand dissociation is required for formation of the active catalytic species.
• Has reactivity profile similar to the Grubbs 1st Generation Catalyst but is active at much lower temperatures (below 0 °C).1

参考文献