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RuCl(p-异丙基甲苯)[(S,S)-Ts-DPEN]_分子结构_CAS_192139-90-5)
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RuCl(p-异丙基甲苯)[(S,S)-Ts-DPEN]

产品号 703915 公司名称 Sigma Aldrich
CAS号 192139-90-5 公司网站 http://www.sigmaaldrich.com
分子式 C31H35ClN2O2RuS 电 话 1-800-521-8956
分子量 636.2098 传 真
纯 度 电子邮件
保 存 Chembase数据库ID: 142488

产品价格信息

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产品别名

标题
RuCl(p-cymene)[(S,S)-Ts-DPEN]
IUPAC标准名
1-methyl-4-(propan-2-yl)benzene; N-[(1S,2S)-2-amino-1,2-diphenylethyl]-N-(chlororuthenio)-4-methylbenzene-1-sulfonamide
IUPAC传统名
N-[(1S,2S)-2-amino-1,2-diphenylethyl]-N-(chlororuthenio)-4-methylbenzenesulfonamide; cymene
别名
[N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium
[N-[(1S,2S)-2-(氨基-κN)-1,2-二苯基乙基]-4-甲基苯磺酰胺合-κN]氯[(1,2,3,4,5,6-η)-1-甲基-4-(1-甲基乙基)苯]-钌

产品登记号

CAS号 192139-90-5
MDL号 MFCD14155881

产品性质

Empirical Formula (Hill Notation) C31H35ClN2O2RuS
熔点 >175 °C
比旋光度 [α]20/D +178°, c = 0.5 in chloroform
MSDS下载 下载链接
个人保护装置 Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
保存温度 2-8°C
德国WGK号 3

产品详细信息

详细说明 (English)
Packaging
100, 500 mg in glass bottle
Legal Information
Sold in collaboration with Takasago for research purposes only. WO9720789
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst involved in:
• Asymmetric transfer hydrogenation of imines and ketones
• Intramolecular asymmetric reductive amination
• Tandem hydroformylation / hydrogenation of terminal olefinsReactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes
详细说明 (简体中文)
包装
100, 500 mg in glass bottle
Legal Information
与 Takasago 合作销售,仅用于研究目的。WO9720789
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst involved in:
• Asymmetric transfer hydrogenation of imines and ketones
• Intramolecular asymmetric reductive amination
• Tandem hydroformylation / hydrogenation of terminal olefinsReactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes

参考文献