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(R)-C3-TunePhos

产品号 650862 公司名称 Sigma Aldrich
CAS号 301847-89-2 公司网站 http://www.sigmaaldrich.com
分子式 C39H32O2P2 电 话 1-800-521-8956
分子量 594.617702 传 真
纯 度 电子邮件
保 存 Chembase数据库ID: 141656

产品价格信息

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产品别名

标题
(R)-C3-TunePhos
IUPAC标准名
[17-(diphenylphosphanyl)-8,12-dioxatricyclo[11.4.0.02,7]heptadeca-1(13),2(7),3,5,14,16-hexaen-3-yl]diphenylphosphane
IUPAC传统名
[17-(diphenylphosphanyl)-8,12-dioxatricyclo[11.4.0.02,7]heptadeca-1(13),2(7),3,5,14,16-hexaen-3-yl]diphenylphosphane
别名
(R)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin
(R)-(-)-1,13-二(二苯基膦)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬四烯

产品登记号

MDL号 MFCD06658115
PubChem SID 24883784
CAS号 301847-89-2

产品性质

Empirical Formula (Hill Notation) C39H32O2P2
熔点 153-161 °C(lit.)
比旋光度 [α]20/D -252±5°, c = 1 in chloroform
MSDS下载 下载链接
个人保护装置 Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
德国WGK号 3

产品详细信息

详细说明 (English)
Application
Provides comparable or superior enantioselectivities and catalytic abilities to BINAP in Ru-catalyzed asymmetric hydrogenations of β-keto esters,6 cyclic β-(acylamino)acrylates7 and α-phthalimide ketones.8
Chiral Quest Phosphine Ligands for Asymmetric HydrogenationLigand used in:
• Redox-neutral domino reaction of arylethynylbenzylidenearylpentynones catalyzed by gold catalyst1
• Asymmetric allylic O-alkylation2
• Asymmetric alkylation of racemic secondary phosphines catalyzed by ruthenium chiral diphosphine hydride complexes3
• Stereoselective preparation of cyclopropylcarboxaldehydes via Rh-catalyzed asymmetric hydroformylation of cyclopropenes4
• Rhodium-catalyzed asymmetric hydrogenations5
Packaging
100, 500 mg in glass bottle
详细说明 (简体中文)
Application
在钌催化的 β-酮酯6、环 β-(酰胺基)丙烯酸酯7和 α-邻苯二甲酰亚胺酮8的不对称性氢化反应中可以提供与 BINAP 相当或更好的对映选择性以及催化能力。
Chiral Quest Phosphine Ligands for Asymmetric HydrogenationLigand used in:
• Redox-neutral domino reaction of arylethynylbenzylidenearylpentynones catalyzed by gold catalyst1
• Asymmetric allylic O-alkylation2
• Asymmetric alkylation of racemic secondary phosphines catalyzed by ruthenium chiral diphosphine hydride complexes3
• Stereoselective preparation of cyclopropylcarboxaldehydes via Rh-catalyzed asymmetric hydroformylation of cyclopropenes4
• Rhodium-catalyzed asymmetric hydrogenations5
包装
100, 500 mg in glass bottle

参考文献