(11bR)-2,6-二-9-菲基-4-羟基-二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英-4-氧化物

• 产品号: 700665
• CAS号: 864943-22-6
• 分子式: C48H29O4P
• 分子量: 700.715221

产品别名

• 标题: (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
• IUPAC标准名: 13-hydroxy-10,16-bis(phenanthren-9-yl)-12,14-dioxa-13λ^5-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-13-one
• IUPAC传统名: 13-hydroxy-10,16-bis(phenanthren-9-yl)-12,14-dioxa-13λ^5-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-13-one
• 别名: (R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate

产品登记号

• CAS号: 864943-22-6
• MDL号: MFCD12546016

产品性质

• Empirical Formula (Hill Notation): C48H29O4P
• 熔点: 390-400 °C
• 比旋光度: [α]22/D -44.0°, c = 1 in DMSO
• 个人保护装置: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• 保存温度: -20°C
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Packaging
100 mg in glass bottle
Application
Catalyst for:
• Asymmetric hydrogenation cascade1
• Enantioselective Friedel-Crafts reaction2
• Asymmetric hydrogenation of 2-substituted quinolines3
• Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates4
• Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters5
• Asymmetric transfer hydrogenation of substituted quinoxalines6

详细说明 (简体中文)

包装
100 mg in glass bottle
Application
Catalyst for:
• Asymmetric hydrogenation cascade1
• Enantioselective Friedel-Crafts reaction2
• Asymmetric hydrogenation of 2-substituted quinolines3
• Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates4
• Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters5
• Asymmetric transfer hydrogenation of substituted quinoxalines6