(R)-3,3′-双[3,5-双(三氟甲基)苯基]-1,1′-联萘-2,2′-二基磷酸氢酯

• 产品号: 674605
• CAS号: 791616-62-1
• 分子式: C36H17F12O4P
• 分子量: 772.4723794
• 纯 度: 95%

产品别名

• 标题: (R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
• IUPAC标准名: 10,16-bis[3,5-bis(trifluoromethyl)phenyl]-13-hydroxy-12,14-dioxa-13λ^5-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-one
• IUPAC传统名: 10,16-bis[3,5-bis(trifluoromethyl)phenyl]-13-hydroxy-12,14-dioxa-13λ^5-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-one
• 别名: (11bR)-2,6-双[3,5-双(三氟甲基)苯基]-4-羟基二萘并[2,1-d:1′,2′-f]-1,3,2-二噁磷杂庚英 4-氧化物; (11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxydinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin 4-oxide; (R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-bi-2-naphthol cyclic monophosphate; (R)-3,3′-双[3,5-双(三氟甲基)苯基]-1,1′-二-2-萘酚环一磷酸酯

产品登记号

• CAS号: 791616-62-1
• MDL号: MFCD08689863
• PubChem SID: 24885225

产品性质

• Empirical Formula (Hill Notation): C36H17F12O4P
• 纯度: 95%
• 熔点: 162-175 °C
• 比旋光度: [α]20/D -220°, c = 1 in chloroform (typical)
• GHS警示词: Warning
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves
• GHS警示性声明: P261-P305 + P351 + P338
• 危险公开号: 36/37/38
• 安全公开号: 26
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
As a chiral Bronsted acid, BINOL- derived cyclic phosphoric acid (such as Akiyama chiral Bronsted acid) was also shown to be an efficient catalyst for the hydrophosphonylation of aldimines at room temperature.1
Packaging
100 mg in glass bottle
Protocols & Applications
Reductive Amination using BINOL-Derived Chiral Phosphoric Acids

详细说明 (简体中文)

Application
作为手性布朗斯特酸，BINOL- 衍生的环磷酸（例如 Akiyama 手性布朗斯特酸）还被证明为室温下亚胺醛磷酰化的高效催化剂。1
包装
100 mg in glass bottle
Protocols & Applications
Reductive Amination using BINOL-Derived Chiral Phosphoric Acids