三(三甲基硅基)氧乙烯基硅烷

• 产品号: 698180
• CAS号: 861445-91-2
• 分子式: C11H30OSi4
• 分子量: 290.6973

产品别名

• 标题: Tris(trimethylsilyl)silyl vinyl ether
• IUPAC标准名: 2-(ethenyloxy)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane
• IUPAC传统名: 2-(ethenyloxy)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane
• 别名: Tris(trimethylsilyl)silyloxyethylene; 乙烯氧基三(三甲基硅基)硅烷; 三(三甲基硅基)硅氧基乙烯; Vinyloxytris(trimethylsilyl)silane

产品登记号

• CAS号: 861445-91-2
• MDL号: MFCD11656064

产品性质

• 熔点: 51-61 °C
• 闪点: 77 °C
• 闪点: 170.6 °F
• GHS警示词: Warning
• GHS危险声明: H228-H315-H319-H335
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 个人保护装置: Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• GHS警示性声明: P210-P261-P305 + P351 + P338
• RID/ADR: UN 1325 4.1/PG 3
• 危险公开号: 11-36/37/38
• 安全公开号: 26-36/37
• 保存温度: 2-8°C
• 联合国危险货物等级: 4.1
• 联合国危险货物编号: 1325
• 联合国危险货物包装类别(PG): 3
• 德国WGK号: 3
• Empirical Formula (Hill Notation): C11H30OSi4

产品详细信息

详细说明 (English)

Packaging
500 mg in glass bottle
Application
Super Silyl Protecting GroupsUsed for:
• Diastereoselective [2+2] cyclizations1
• Cross-Aldol cascade reaction2,3
• Diastereoselective sequential reactions for generating polyols4,5
• Accessing distinct diastereomers and 4-component reactions6
• Supersilyl-directed aldol reactions7
• Strong electron-donating effect of the supersilyl group operates only in the α-position and not in the β-position8

详细说明 (简体中文)

包装
500 mg in glass bottle
Application
Super Silyl Protecting GroupsUsed for:
• Diastereoselective [2+2] cyclizations1
• Cross-Aldol cascade reaction2,3
• Diastereoselective sequential reactions for generating polyols4,5
• Accessing distinct diastereomers and 4-component reactions6
• Supersilyl-directed aldol reactions7
• Strong electron-donating effect of the supersilyl group operates only in the α-position and not in the β-position8