(R)-(+)-(6,6′-二甲氧联苯-2,2′-二基)双(二苯基膦)

• 产品号: 29510
• CAS号: 133545-16-1
• 分子式: C38H32O2P2
• 分子量: 582.607002
• 纯 度: ≥97%

产品别名

• 标题: (R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
• IUPAC标准名: {2-[2-(diphenylphosphanyl)-6-methoxyphenyl]-3-methoxyphenyl}diphenylphosphane
• IUPAC传统名: {2-[2-(diphenylphosphanyl)-6-methoxyphenyl]-3-methoxyphenyl}diphenylphosphane
• 别名: (R)-(+)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl; SL-A101-1; (R)-(+)-2,2′-双(二苯基膦)-6,6′-二甲氧-1,1′-联苯; (R)-(+)-MeO-BIPHEP

产品登记号

• PubChem SID: 24857757
• CAS号: 133545-16-1
• Beilstein号: 4790083
• MDL号: MFCD03095430

产品性质

• Empirical Formula (Hill Notation): C38H32O2P2
• 光学纯度: ee: ≥99%
• 纯度: ≥97%
• 个人保护装置: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Atropisomeric diphosphine; the Rh(I) complex is employed for highly enantioselective asymmetric isomerization of allylamines to enamines4,5; the Ru(II) complex hydrogenates β-keto esters in high enantioselectivity6,7; the Pd(0) complex for cyclization of hydroxy allylic carbonates8.
Atropisomeric MeOBIPHEP ligands
• Hydrogenation of α- and β-functionalized ketones1
• Hydrogenation of heteroarenes2
• C-C coupling reactions3
General description
sold in collaboration with Solvias AG
Packaging
1, 5 g in glass bottle
100, 500 mg in glass bottle

详细说明 (简体中文)

Application
阻旋异构双膦；Rh(I) 络合物可用于烯丙胺至烯胺的高对映选择性不对称异构化4,5；Ru(II) 络合物以高对映选择性氢化 β-酮酯6,7；Pd(0) 络合物用于羟基烯丙基碳酸酯的环化8。
Atropisomeric MeOBIPHEP ligands
• Hydrogenation of α- and β-functionalized ketones1
• Hydrogenation of heteroarenes2
• C-C coupling reactions3
General description
与 Solvias AG 联合销售
包装
1, 5 g in glass bottle
100, 500 mg in glass bottle