(S)-(-)-(6,6′-二甲氧联苯-2,2′-二基)双(二苯基膦)

• 产品号: 29511
• CAS号: 133545-17-2
• 分子式: C38H32O2P2
• 分子量: 582.607002
• 纯 度: ≥97%

产品别名

• 标题: (S)-(-)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
• IUPAC标准名: {2-[2-(diphenylphosphanyl)-6-methoxyphenyl]-3-methoxyphenyl}diphenylphosphane
• IUPAC传统名: {2-[2-(diphenylphosphanyl)-6-methoxyphenyl]-3-methoxyphenyl}diphenylphosphane
• 别名: (S)-(-)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl; SL-A101-2; (S)-(-)-MeO-BIPHEP; (S)-(-)-2,2′-双(二苯基膦)-6,6′-二甲氧-1,1′-联苯

产品登记号

• CAS号: 133545-17-2
• Beilstein号: 4790083
• PubChem SID: 24857759
• MDL号: MFCD03095430

产品性质

• Empirical Formula (Hill Notation): C38H32O2P2
• 光学纯度: ee: ≥99%
• 纯度: ≥97%
• 个人保护装置: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• 德国WGK号: 3

产品详细信息

详细说明 (English)

General description
sold in collaboration with Solvias AG
Packaging
1, 5 g in glass bottle
100, 500 mg in glass bottle
Application
Atropisomeric MeOBIPHEP ligands
• C-C coupling reactions1
• Ligand for palladium-catalyzed intramolecular allylic alkylation of unsaturated amides2
• Enantioselective hydrogenation of a-amino-β-keto ester hydrochlorides catalyzed by an iridium complex3
• Asymmetric hydrogenation of aromatic ketones4

详细说明 (简体中文)

General description
与 Solvias AG 联合销售
包装
1, 5 g in glass bottle
100, 500 mg in glass bottle
Application
Atropisomeric MeOBIPHEP ligands
• C-C coupling reactions1
• Ligand for palladium-catalyzed intramolecular allylic alkylation of unsaturated amides2
• Enantioselective hydrogenation of a-amino-β-keto ester hydrochlorides catalyzed by an iridium complex3
• Asymmetric hydrogenation of aromatic ketones4