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氯二羰基(1,2,3,4,5-五苯基环戊二烯基)钌(II)_分子结构_CAS_677736-23-1)
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氯二羰基(1,2,3,4,5-五苯基环戊二烯基)钌(II)

产品号 686441 公司名称 Sigma Aldrich
CAS号 677736-23-1 公司网站 http://www.sigmaaldrich.com
分子式 C37H25ClO2Ru 电 话 1-800-521-8956
分子量 638.1162 传 真
纯 度 电子邮件
保 存 Chembase数据库ID: 140431

产品价格信息

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产品别名

标题
Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)
IUPAC标准名
chlororutheniumylium; bis(methanidylidyneoxidanium); pentaphenylcyclopenta-2,4-dien-1-ide
IUPAC传统名
bis(carbon monoxide); chlororutheniumylium; pentaphenylcyclopenta-2,4-dien-1-ide
别名
二羰基氯[(1,2,3,4,5,-η)-1,2,3,4,5-五苯基环-2,4-戊二烯-1-基)]钌
Dicarbonylchloro[(1,2,3,4,5,-η)-1,2,3,4,5-pentaphenylcyclo-2,4-pentadien-1-yl)]ruthenium

产品登记号

CAS号 677736-23-1
MDL号 MFCD09265041

产品性质

Empirical Formula (Hill Notation) C37H25ClO2Ru
熔点 152-167 °C
GHS危险品标识 GHS07
GHS警示词 Warning
GHS危险声明 H315-H319-H335
欧盟危险性物质标志 刺激性(Irritant) 刺激性(Irritant) (Xi)
MSDS下载 下载链接
个人保护装置 dust mask type N95 (US), Eyeshields, Gloves
GHS警示性声明 P261-P305 + P351 + P338
危险公开号 36/37/38
安全公开号 26
德国WGK号 3

产品详细信息

详细说明 (English)
Packaging
1 g in glass bottle
250 mg in glass bottle
Legal Information
Product of Kanata Chemical Technologies, Inc.
Application
Reactant for:
• Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst1
• Ligand exchange2
• Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds3Catalyst for:
• (S)-Selective dynamic kinetic resolution of secondary alcohols4
• Stereoselective synthesis of neonicorinoide pesticide derivatives5
• Divergent asymmetric synthesis of 3,5-disubstituted piperidines6
Citation
Metal catalyst used in conjunction with enzymes for enantioselective transformations via dynamic kinetic resolution7
详细说明 (简体中文)
包装
1 g in glass bottle
250 mg in glass bottle
Legal Information
Kanata Chemical Technologies, Inc. 产品
Application
Reactant for:
• Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst1
• Ligand exchange2
• Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds3Catalyst for:
• (S)-Selective dynamic kinetic resolution of secondary alcohols4
• Stereoselective synthesis of neonicorinoide pesticide derivatives5
• Divergent asymmetric synthesis of 3,5-disubstituted piperidines6
Citation
用于与酶共同作用,通过动态动力学拆分来催化不对称转化的金属催化剂7

参考文献