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甲氧基(环辛二烯)合铱二聚体_分子结构_CAS_12148-71-9)
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甲氧基(环辛二烯)合铱二聚体

产品号 685062 公司名称 Sigma Aldrich
CAS号 12148-71-9 公司网站 http://www.sigmaaldrich.com
分子式 C18H30Ir2O2 电 话 1-800-521-8956
分子量 662.8636 传 真
纯 度 电子邮件
保 存 Chembase数据库ID: 89870

产品价格信息

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产品别名

标题
(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
IUPAC标准名
bis(cycloocta-1,5-diene); dimethyl-2,4-dioxa-1,3-diiridabicyclo[1.1.0]butane-2,4-diium-1,3-diuide
IUPAC传统名
bis(1,5-cyclooctadiene); dimethyl-2,4-dioxa-1,3-diiridabicyclo[1.1.0]butane-2,4-diium-1,3-diuide
别名
二(1,5-环辛二烯)二-Μ-甲氧基二铱(I)
Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I)
[Ir(OMe)(1,5-cod)]2

产品登记号

MDL号 MFCD08459360
CAS号 12148-71-9

产品性质

线性分子式 [Ir(OCH3)(C8H12)]2
熔点 154-179 °C (D)
GHS危险品标识 GHS07
GHS警示词 Warning
GHS危险声明 H315-H319-H335
欧盟危险性物质标志 刺激性(Irritant) 刺激性(Irritant) (Xi)
MSDS下载 下载链接
个人保护装置 dust mask type N95 (US), Eyeshields, Gloves
GHS警示性声明 P261-P305 + P351 + P338
危险公开号 36/37/38
安全公开号 26
德国WGK号 3

产品详细信息

详细说明 (English)
Packaging
1 g in glass bottle
250 mg in glass bottle
Application
Catalyst for:
• Preparation of heteroaryl fused indole ring systems as inhibitors of HCV NS5B polymerase1
• Borylation/Suzuki-Miyaura coupling2
• Metalation-Suzuki cross-coupling procedure for the synthesis of biaryls and heterobiaryls3
• Tetraborylation reactions4
• Highly regio- and enantioselective asymmetric hydroboration5
• Ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation6
Citation
A powerful C-H activation catalyst to prepare phenols from arenes7
详细说明 (简体中文)
包装
1 g in glass bottle
250 mg in glass bottle
Application
Catalyst for:
• Preparation of heteroaryl fused indole ring systems as inhibitors of HCV NS5B polymerase1
• Borylation/Suzuki-Miyaura coupling2
• Metalation-Suzuki cross-coupling procedure for the synthesis of biaryls and heterobiaryls3
• Tetraborylation reactions4
• Highly regio- and enantioselective asymmetric hydroboration5
• Ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation6
Citation
一种强效的 C-H 键活化催化剂,可用于由芳烃制备酚。7

参考文献