RuCl2[(S)-(DM-BINAP)][(S)-DAIPEN]

• 产品号: 693227
• CAS号: 220114-01-2
• 分子式: C71H72Cl2N2O2P2Ru
• 分子量: 1219.267102

产品别名

• 标题: RuCl2[(S)-(DM-BINAP)][(S)-DAIPEN]
• IUPAC标准名: (4S)-1,1-dichloro-12',12',14',14'-tetrakis(3,5-dimethylphenyl)-3,3-bis(4-methoxyphenyl)-4-(propan-2-yl)-2,5-diaza-12'λ^5,14'λ^5-diphospha-1-ruthenaspiro[cyclopentane-1,13'-pentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosane]-1'(15'),2',4',6',8',10',16',18',20',22'-decaene
• IUPAC传统名: (4S)-1,1-dichloro-12',12',14',14'-tetrakis(3,5-dimethylphenyl)-4-isopropyl-3,3-bis(4-methoxyphenyl)-2,5-diaza-12'λ^5,14'λ^5-diphospha-1-ruthenaspiro[cyclopentane-1,13'-pentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosane]-1'(15'),2',4',6',8',10',16',18',20',22'-decaene
• 别名: Dichloro[(S)-(-)-2,2′-bis[di(3,5-xylyl)phosphino]-1,1′-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II); 二氯[(S)-(-)-2,2′-二[二(3,5-二甲苯基)膦基]-1,1′-联萘基][(2S)-(+)-1,1-二(4-甲氧苯基)-3-甲基-1,2-丁二胺]钌(II)

产品登记号

• CAS号: 220114-01-2

产品性质

• Empirical Formula (Hill Notation): C71H74Cl2N2O2P2Ru
• GHS警示词: Warning
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• GHS警示性声明: P261-P305 + P351 + P338
• 危险公开号: 36/37/38
• 安全公开号: 26
• 保存温度: 2-8°C
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Packaging
50, 100 mg in glass bottle
Legal Information
Sold in collaboration with Takasago for research purposes only. JP Registration No. 2041996, 2731377, 2935453 JP Appllication No. 19970359654
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst for:
• Preparation of cyclometalated ruthenium 1,1-dianisyl-2-isopropyl-1,2-ethylenediamine complexes via asymmetric hydrogenation of ketones
• Enantioselective hydrogenation of an α-alkoxy substituted ketone with chiral ruthenium (phosphinoferrocenyl)oxazoline complexes
• Nonclassical asymmeteric hydrogen transfer between alcohols and carbonyl compounds
• Asymmetric hydrogenation of amino and heteroaromatic ketones
• Pharmacologically active substituted oxazolidinone used as NPC1L1 ligand for inhibition of cholesterol absorption

详细说明 (简体中文)

包装
50, 100 mg in glass bottle
Legal Information
与 Takasago 合作销售，仅用于研究目的。日本注册号 041996, 2731377, 2935453，日本申请号19970359654
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst for:
• Preparation of cyclometalated ruthenium 1,1-dianisyl-2-isopropyl-1,2-ethylenediamine complexes via asymmetric hydrogenation of ketones
• Enantioselective hydrogenation of an α-alkoxy substituted ketone with chiral ruthenium (phosphinoferrocenyl)oxazoline complexes
• Nonclassical asymmeteric hydrogen transfer between alcohols and carbonyl compounds
• Asymmetric hydrogenation of amino and heteroaromatic ketones
• Pharmacologically active substituted oxazolidinone used as NPC1L1 ligand for inhibition of cholesterol absorption