乙酰基硫甲基-硼烷二苯基膦复合物

• 产品号: 670359
• CAS号: 446822-71-5
• 分子式: C15H18BOPS
• 分子量: 288.152581
• 纯 度: ≥98.0%

产品别名

• 标题: Acetylthiomethyl-diphenylphosphine borane complex
• IUPAC标准名: 1-{[(diphenylphosphanyl)methyl]sulfanyl}ethan-1-one borane
• IUPAC传统名: 1-{[(diphenylphosphanyl)methyl]sulfanyl}ethanone borane

产品登记号

• CAS号: 446822-71-5

产品性质

• Empirical Formula (Hill Notation): C15H18BOPS
• 纯度: ≥98.0%
• 熔点: 52-55 °C
• GHS警示词: Warning
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves
• GHS警示性声明: P261-P305 + P351 + P338
• 危险公开号: 36/37/38
• 安全公开号: 26
• 保存温度: 2-8°C
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Packaging
1 g in glass bottle
250 mg in glass bottle
Legal Information
Sold under license for research and development purposes only. US Patent 6,974,884 and related patents apply
Application

• Traceless Staudinger ligation reagent with borane protecting group.
• The borane group stabilizes the phosphine against oxidation and can be easily removed with mild basic or acidic conditions to yield the active phosphine.1
• After reaction with an azide, the phosphine is eliminated in the presence of water to yield a native amide bond.2
• Used in the synthesis of cyclic peptides.2

详细说明 (简体中文)

包装
1 g in glass bottle
250 mg in glass bottle
Legal Information
授权后方可销售，仅供研发使用。美国专利 6,974,884 和相关专利申请
Application

• Traceless Staudinger ligation reagent with borane protecting group.
• The borane group stabilizes the phosphine against oxidation and can be easily removed with mild basic or acidic conditions to yield the active phosphine.1
• After reaction with an azide, the phosphine is eliminated in the presence of water to yield a native amide bond.2
• Used in the synthesis of cyclic peptides.2