(R)-α,α-双[3,5-双(三氟甲基)苯基]-2-吡咯烷甲醇三甲基硅基醚

• 产品号: 677213
• CAS号: 908303-26-4
• 分子式: C24H23F12NOSi
• 分子量: 597.5118584

产品别名

• 标题: (R)-α,α-Bis[3,5-bis(trifluoromethyl)phenyl]-2-pyrrolidinemethanol trimethylsilyl ether
• IUPAC标准名: (2R)-2-{bis[3,5-bis(trifluoromethyl)phenyl][(trimethylsilyl)oxy]methyl}pyrrolidine
• IUPAC传统名: (2R)-2-{bis[3,5-bis(trifluoromethyl)phenyl][(trimethylsilyl)oxy]methyl}pyrrolidine
• 别名: (R)-2-[(Bis(3,5-bis(trifluoromethyl)phenyl)]trimethylsilanyloxy)methyl]pyrrolidine; (R)-2-[(Bis(3,5-bis(trifluoromethyl)phenyl)]trimethylsilyloxy)methyl]pyrrolidine; (R)-2-[(双(3,5-双(三氟甲基)苯基)]三甲基硅烷氧基)甲基]吡咯烷; (R)-α,α-Bis[3,5-bis(trifluoromethyl)phenyl]prolinol trimethylsilyl ether; (R)-α,α-双[3,5-双(三氟甲基)苯基]脯氨醇三甲基硅醚; (R)-2-[(双(3,5-双(三氟甲基)苯基)]三甲基甲硅氧基)甲基]吡咯烷

产品登记号

• PubChem SID: 24885357
• MDL号: MFCD09750448
• CAS号: 908303-26-4

产品性质

• Empirical Formula (Hill Notation): C24H23F12NOSi
• 级别: technical grade
• 光学纯度: enantiomeric excess: ≥99.0% (HPLC)
• 闪点: >110 °C
• 闪点: >230 °F
• 熔点: 46-55 °C
• GHS警示词: Warning
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves
• GHS警示性声明: P261-P305 + P351 + P338
• 危险公开号: 36/37/38
• 安全公开号: 26
• 德国WGK号: 3

产品详细信息

详细说明 (简体中文)

包装
1, 5 g in glass bottle
Application
Catalyst involved in:
• Cyclocondensation of enals with methylenepyrrolidines1
• Organocatalytic additions of β-ketosulfoxides to conjugated aldehydes2
• Organocatalytic aza-Michael reactions3,4
• Stereoselective propargylic alkylation of propargylic esters with aldehydes5
• Epoxidation or aziridination of α,β-unsaturated aldehydes and Feist-Benary reactions of 1,3-dicarbonyls6
Protocols & Applications
Asymmetric a-Functionalization of Aldehydes using J??rgensen's Organocatalysts

详细说明 (English)

Packaging
1, 5 g in glass bottle
Application
Catalyst involved in:
• Cyclocondensation of enals with methylenepyrrolidines1
• Organocatalytic additions of β-ketosulfoxides to conjugated aldehydes2
• Organocatalytic aza-Michael reactions3,4
• Stereoselective propargylic alkylation of propargylic esters with aldehydes5
• Epoxidation or aziridination of α,β-unsaturated aldehydes and Feist-Benary reactions of 1,3-dicarbonyls6
Protocols & Applications
Asymmetric a-Functionalization of Aldehydes using J?rgensen's Organocatalysts