(S,R,R)-(+)-(3,5-二氧杂-4-磷杂环庚二烯并[2,1-a:3,4-a′]二萘-4-基)二(1-苯基乙基)胺

• 产品号: 665363
• CAS号: 415918-91-1
• 分子式: C36H50NO2P
• 分子量: 559.761461
• 纯 度: 97% (HPLC)

产品别名

• 标题: (S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine
• IUPAC标准名: N,N-bis[(1R)-1-phenylethyl]-12,14-dioxa-13-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosan-13-amine
• IUPAC传统名: N,N-bis[(1R)-1-phenylethyl]-12,14-dioxa-13-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosan-13-amine
• 别名: (+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine, (11bS)

产品登记号

• CAS号: 415918-91-1
• MDL号: MFCD08561138
• PubChem SID: 24884733

产品性质

• Empirical Formula (Hill Notation): C36H30NO2P
• 纯度: 97% (HPLC)
• 熔点: 102-103 °C
• 个人保护装置: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Chiral phosphoramidite ligand used in a highly enantioselective copper-catalyzed conjugate addition of diakylzincs to a variety of Michael acceptors.1,2,3 Also used in a palladium-catalyzed diethylzinc mediated umpolung allylation.4
DSM MonoPhos Family of Highly Efficient Privileged Ligands
Packaging
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
Sold under license from DSM for research purposes only.

详细说明 (简体中文)

Application
手性亚磷酰胺配体，用于铜催化的高对映选择性共轭加成反应，该反应可将二烷基锌加成到各种 Michael 受体。1,2,3也可用于二乙基锌介导的钯催化极性反转烯丙基化反应。4
DSM MonoPhos Family of Highly Efficient Privileged Ligands
包装
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
经 DSM 授权销售，仅供研究使用。