N-叔丁基苯亚磺酰胺

• 产品号: 681792
• CAS号: 19117-31-8
• 分子式: C10H15NS
• 分子量: 181.2978
• 纯 度: 97%

产品别名

• 标题: N-tert-Butylbenzenesulfenamide
• IUPAC标准名: tert-butyl(phenylsulfanyl)amine
• IUPAC传统名: tert-butyl(phenylsulfanyl)amine
• 别名: N-(1,1-Dimethylethyl)benzenesulfenamide; N-叔丁基苯磺酰胺; N-(1,1-二甲基乙基)苯亚磺酰胺; 2-Methyl-N-(phenylthio)propan-2-amine

产品登记号

• CAS号: 19117-31-8
• PubChem SID: 24885655
• MDL号: MFCD03844776

产品性质

• 纯度: 97%
• Empirical Formula (Hill Notation): C10H15NS
• 沸点: 57-60 °C/0.3 mmHg
• 密度: 0.997 g/mL at 25 °C
• 闪点: 96 °C
• 闪点: 204.8 °F
• 折射率: n20/D 1.5457
• 个人保护装置: Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
In the presence of NCS, this sulfenamide catalyzes the mild and selective oxidation of primary and secondary alcohols to the respective aldehydes and ketones.3
Reactant for:
• Anti-SN2′ Mitsunobu reaction with chiral hydroxy-alpha-alkenylsilanes to give vinylsilanes1
• Anodic oxidation reactions2
Packaging
1, 5 g in glass bottle

详细说明 (简体中文)

Application
在 NCS 存在的条件下，这种亚磺酰胺可催化伯醇和仲醇的温和选择性氧化反应，分别生成醛和酮。3
Reactant for:
• Anti-SN2′ Mitsunobu reaction with chiral hydroxy-alpha-alkenylsilanes to give vinylsilanes1
• Anodic oxidation reactions2
包装
1, 5 g in glass bottle