(+)-9-(1S, 2S-伪麻黄碱基)-(10R)-(三甲基硅基)-9-硼杂双环[3.3.2]癸烷

• 产品号: 676675
• CAS号: 848618-13-3
• 分子式: C22H38BNOSi
• 分子量: 371.43972

产品别名

• 标题: (+)-9-(1S, 2S-Pseudoephedrinyl)-(10R)-(trimethylsilyl)-9-borabicyclo[3.3.2]decane
• IUPAC标准名: methyl[(1S,2S)-1-phenyl-1-{[(1S,5s,10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]decan-9-yl]oxy}propan-2-yl]amine
• IUPAC传统名: methyl[(1S,2S)-1-phenyl-1-{[(1S,5s,10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]decan-9-yl]oxy}propan-2-yl]amine
• 别名: N,α-Dimethyl-β-[[(10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]dec-9-yl]oxy]-(αS,βS)-benzeneethanamine; N,α-二甲基-β-[[(10R)-10-(三甲基硅基)-9-硼杂双环[3.3.2]癸-9-基]氧]-(αS,βS)-苯乙胺

产品登记号

• PubChem SID: 24885323
• CAS号: 848618-13-3
• MDL号: MFCD09265094

产品性质

• Empirical Formula (Hill Notation): C22H38BNOSi
• 熔点: 130-134 °C
• 比旋光度: [α]22/D +60°, c = 4.5 in chloroform-d
• GHS警示词: Warning
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves
• GHS警示性声明: P261-P305 + P351 + P338
• 危险公开号: 36/37/38
• 安全公开号: 26
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Air-stable, crystalline pseudoephedrine borinic acid complex which when treated with an appropriate Grignard reagent provides access to homoallylic or homopropargylic alcohols and α-allenyl carbinols.1,2,3
Soderquist Reagents: For allylboration, allenylboration, propargylboration
Packaging
1, 5 g in glass bottle

详细说明 (简体中文)

Application
在空气中稳定的结晶伪麻黄碱硼酸络合物，当用适当的格氏试剂处理后，可与高烯丙醇或高丙炔醇以及 α-联烯基甲醇反应。1,2,3
Soderquist Reagents: For allylboration, allenylboration, propargylboration
包装
1, 5 g in glass bottle