羟基[-(S)-BINAP]-铑(I) 二聚体

• 产品号: 661007
• 分子式: C88H66O2P4Rh2
• 分子量: 1485.170484
• 纯 度: 90%

产品别名

• 标题: Hydroxy[-(S)-BINAP]-rhodium(I) Dimer
• IUPAC标准名: bis(rhodiumol); bis({1-[2-(diphenylphosphanyl)naphthalen-1-yl]naphthalen-2-yl}diphenylphosphane)
• IUPAC传统名: bis(binap); bis(rhodiumol)

产品登记号

• PubChem SID: 24884495
• MDL号: MFCD08561132

产品性质

• Empirical Formula (Hill Notation): C88H66O2P4Rh2
• 杂质: 3-5% THF
• 杂质: 3-5% ethanol
• 纯度: 90%
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Catalyst employed in an asymmetric 1,6-addition of arylzinc reagents to dienones leading to chiral 5-substituted enones.1 Also used in an asymmetric 1,4-addition of organoboron reagents to cyclic and acyclic α,β-unsaturated ketones with excellent enantioselectivity.2
Efficient and Selective Catalysts for Asymmetric Synthesis
Packaging
1 g in glass bottle
250 mg in glass bottle

详细说明 (简体中文)

Application
催化剂，用于芳基锌试剂不对称 1,6-加成到二烯酮，生成手性 5-取代烯酮。1还用于有机硼试剂不对称 1,4-加成到具有高对映选择性的环及非环 α,β-不饱和酮。2
Efficient and Selective Catalysts for Asymmetric Synthesis
包装
1 g in glass bottle
250 mg in glass bottle